[(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Base Information

Chemical Name:[(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride
CAS No.:461003-69-0
Molecular Formula:C₁₃H₁₆ClOP
Molecular Weight:254.696
Hs Code.:

Synonyms:[(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Suppliers and Price of [(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

There total 6 articles about [(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 461003-68-9
[(4E)-hepta-4,6-dienyl](phenyl)phosphinic acid

: 461003-69-0
[(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Guidance literature:: [(4E)-hepta-4,6-dienyl](phenyl)phosphinic acid; With N,N-diethyl-1,1,1-trimethylsilanamine; In dichloromethane; at 0 ℃; for 2h;

With oxalyl dichloride; In dichloromethane; at 0 - 20 ℃; for 2.75h; Further stages.;
DOI:10.1021/jo0202839

Reference yield:

: 55048-74-3
(4E)-hepta-4,6-dien-1-ol

: 461003-69-0
[(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Guidance literature:: Multi-step reaction with 5 steps

1.1: 69 percent / 1,4-diazabicyclo[2.2.2]octane / CH₂Cl₂ / 96 h / 20 °C

2.1: LiBr / acetone / 16 h / Heating

3.1: 63 percent / 5 h / Heating

4.1: 98 percent / NaOH / ethanol / 2.5 h / Heating

5.1: N,N-diethyltrimethylsilylamine / CH₂Cl₂ / 2 h / 0 °C

5.2: oxalyl chloride / CH₂Cl₂ / 2.75 h / 0 - 20 °C

With 1,4-diaza-bicyclo[2.2.2]octane; sodium hydroxide; N,N-diethyl-1,1,1-trimethylsilanamine; lithium bromide; In ethanol; dichloromethane; acetone;
DOI:10.1021/jo0202839

Reference yield:

: 128845-45-4
toluene-4-sulfonic acid (4E)-hepta-4,6-dien-1-yl ester

: 461003-69-0
[(4E)-hepta-4,6-dienyl](phenyl)phosphinic chloride

Guidance literature:: Multi-step reaction with 4 steps

1.1: LiBr / acetone / 16 h / Heating

2.1: 63 percent / 5 h / Heating

3.1: 98 percent / NaOH / ethanol / 2.5 h / Heating

4.1: N,N-diethyltrimethylsilylamine / CH₂Cl₂ / 2 h / 0 °C

4.2: oxalyl chloride / CH₂Cl₂ / 2.75 h / 0 - 20 °C

With sodium hydroxide; N,N-diethyl-1,1,1-trimethylsilanamine; lithium bromide; In ethanol; dichloromethane; acetone;
DOI:10.1021/jo0202839