C₂₁H₂₅NO₆

Base Information

• Chemical Name: C₂₁H₂₅NO₆
• CAS No.: 1450751-94-6
• Molecular Formula: C₂₁H₂₅NO₆
• Molecular Weight: 387.433
• Mol file: 1450751-94-6.mol

Synonyms:C₂₁H₂₅NO₆

Chemical Property of C₂₁H₂₅NO₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₁H₂₅NO₆

There total 5 articles about C₂₁H₂₅NO₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

salicylaldehyde (90-02-8) + C-(4,6-O-benzylidene-β-D-glucopyranosyl) methylamine (136738-62-0) → C21H25NO6 (1450751-94-6)

Guidance literature:

salicylaldehyde; C-(4,6-O-benzylidene-β-D-glucopyranosyl) methylamine; In ethanol; Inert atmosphere; Reflux;

With sodium tetrahydroborate; In methanol; at 20 ℃; for 0.5h;

DOI:10.1016/j.bmc.2013.06.002

Reference yield:

4,6-O-benzylidene-D-glucose (3006-41-5,20771-09-9,25152-90-3,97232-16-1,104022-77-7,113566-67-9,113566-68-0) → C21H25NO6 (1450751-94-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 48 h / 20 °C / Inert atmosphere

2.1: ammonium formate; palladium 10% on activated carbon / methanol / 3 h / 65 °C

3.1: ethanol / Inert atmosphere; Reflux

3.2: 0.5 h / 20 °C

With palladium 10% on activated carbon; ammonium formate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; methanol; ethanol;

DOI:10.1016/j.bmc.2013.06.002

Reference yield:

2,6-anhydro-5,7-O-benzylidene-1-deoxy-1-nitro-D-glycero-D-gulo-heptitol (136738-59-5) → C21H25NO6 (1450751-94-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: ammonium formate; palladium 10% on activated carbon / methanol / 3 h / 65 °C

2.1: ethanol / Inert atmosphere; Reflux

2.2: 0.5 h / 20 °C

With palladium 10% on activated carbon; ammonium formate; In methanol; ethanol;

DOI:10.1016/j.bmc.2013.06.002

upstream raw materials:

salicylaldehyde

C-(4,6-O-benzylidene-β-D-glucopyranosyl) methylamine

4,6-O-benzylidene-D-glucose

2,6-anhydro-5,7-O-benzylidene-1-deoxy-1-nitro-D-glycero-D-gulo-heptitol

Downstream raw materials:

N-(β-D-glucopyranosylmethyl)-2-hydroxybenzylamine