3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol

Base Information

• Chemical Name: 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol
• CAS No.: 1359093-52-9
• Molecular Formula: C₆₄H₄₇N₃
• Molecular Weight: 858.097
• Mol file: 1359093-52-9.mol

Synonyms:3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol

Chemical Property of 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol

There total 3 articles about 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

3,6-bis(4-vinyl-phenyl)-9H-carbazole (1359093-62-1) + 4-N,N-diphenylamino-1-bromobenzene (36809-26-4) → 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol (1359093-52-9)

Guidance literature:

With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine; In N,N-dimethyl-formamide; Reflux;

DOI:10.1002/asia.201100661

Reference yield:

4-Vinylphenylboronic acid (2156-04-9,593231-72-2) → 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol (1359093-52-9)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / methanol; water; toluene / 24 h / Reflux

2: palladium diacetate; triethylamine; tris-(o-tolyl)phosphine / N,N-dimethyl-formamide / Reflux

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; palladium diacetate; potassium carbonate; triethylamine; tris-(o-tolyl)phosphine; In methanol; water; N,N-dimethyl-formamide; toluene; 1: Suzuki reaction / 2: Heck reaction;

DOI:10.1002/asia.201100661

Reference yield:

3,6-dibromo-9H-carbazole (6825-20-3) → 3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}-9H-carbazol (1359093-52-9)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / methanol; water; toluene / 24 h / Reflux

2: palladium diacetate; triethylamine; tris-(o-tolyl)phosphine / N,N-dimethyl-formamide / Reflux

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; palladium diacetate; potassium carbonate; triethylamine; tris-(o-tolyl)phosphine; In methanol; water; N,N-dimethyl-formamide; toluene; 1: Suzuki reaction / 2: Heck reaction;

DOI:10.1002/asia.201100661

upstream raw materials:

3,6-bis(4-vinyl-phenyl)-9H-carbazole

4-N,N-diphenylamino-1-bromobenzene

3,6-dibromo-9H-carbazole

4-Vinylphenylboronic acid

Downstream raw materials:

5'-[4-(3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}carbazol-9-yl)phenyl]-[2,2']bithiophenyl-5-carbaldehyde

5'-(3,6-bis{4-[2-(4-diphenylamino-phenyl)vinyl]phenyl}carbazol-9-yl)-[2,2']bithiophenyl-5-carbaldehyde