C₅₉H₉₅NO₁₅Si₃

Base Information

Chemical Name:C₅₉H₉₅NO₁₅Si₃
CAS No.:1393595-30-6
Molecular Formula:C₅₉H₉₅NO₁₅Si₃
Molecular Weight:1142.66
Hs Code.:

C<sub>59</sub>H<sub>95</sub>NO<sub>15</sub>Si<sub>3</sub>

Synonyms:C₅₉H₉₅NO₁₅Si₃

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Chemical Property of C₅₉H₉₅NO₁₅Si₃

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Technology Process of C₅₉H₉₅NO₁₅Si₃

There total 28 articles about C₅₉H₉₅NO₁₅Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1393595-35-1
C₅₃H₈₁NO₁₄Si₂

: 76513-69-4
(2-trimethylethylsilylethoxy)methyl chloride

: 1393595-30-6
C₅₉H₉₅NO₁₅Si₃

Guidance literature:: With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 0 - 20 ℃; for 23.25h; Inert atmosphere;
DOI:10.1021/ol301783p

Reference yield:

: 21852-32-4
4-bromomethyl-1,2-dimethoxybenzene

: 1393595-30-6
C₅₉H₉₅NO₁₅Si₃

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium carbonate / acetone / 24 h / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.33 h / -78 °C / Inert atmosphere

3.1: phenylborondichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere

3.2: -78 - 0 °C / Inert atmosphere

3.3: 4.25 h / -78 °C / Inert atmosphere

4.1: diethyl methoxy borane / methanol; tetrahydrofuran / 0.42 h / -78 °C / Inert atmosphere

4.2: -78 - 0 °C / Inert atmosphere

4.3: 35 h / 20 °C / Inert atmosphere

5.1: N-ethyl-N,N-diisopropylamine / acetone / 1 h / 0 °C / Inert atmosphere

5.2: 0.33 h / 0 °C / Inert atmosphere

6.1: toluene / 0.75 h / 80 °C / Inert atmosphere; Reflux

6.2: 5 h / 80 °C / Inert atmosphere; Reflux

7.1: N-ethyl-N,N-diisopropylamine; tetra-(n-butyl)ammonium iodide / tetrahydrofuran / 23.25 h / 0 - 20 °C / Inert atmosphere

With diethyl methoxy borane; phenylborondichloride; tetra-(n-butyl)ammonium iodide; diisobutylaluminium hydride; potassium carbonate; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; hexane; dichloromethane; acetone; toluene; 6.2: |Curtius Rearrangement;
DOI:10.1021/jo400260m

Reference yield:

: C₁₉H₂₈O₄

: 1393595-30-6
C₅₉H₉₅NO₁₅Si₃

Guidance literature:: Multi-step reaction with 21 steps

1.1: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0.5 h / 20 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere

3.1: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve

4.1: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

5.1: dichloromethane / 0.02 h / 0 °C / Inert atmosphere

6.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere

7.1: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

8.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere

9.1: D-(-)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / 4 h / -20 °C / Inert atmosphere; Molecular sieve

10.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium chlorite / acetonitrile / 1.5 h / pH 7 / Inert atmosphere

11.1: diethyl ether / 0 °C / Inert atmosphere

12.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 0.77 h / 0 °C / pH 7 / Inert atmosphere

13.1: camphor-10-sulfonic acid / dichloromethane / 5 h / 20 °C / Inert atmosphere

14.1: sodium hydride / tetrahydrofuran; mineral oil / 0.33 h / 0 °C / Inert atmosphere

14.2: 1.5 h / 0 - 20 °C / Inert atmosphere

15.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 5 h / 20 °C / Inert atmosphere

16.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 1 h / 0 °C / Inert atmosphere

17.1: phenylborondichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere

17.2: -78 - 0 °C / Inert atmosphere

17.3: 4.25 h / -78 °C / Inert atmosphere

18.1: diethyl methoxy borane / methanol; tetrahydrofuran / 0.42 h / -78 °C / Inert atmosphere

18.2: -78 - 0 °C / Inert atmosphere

18.3: 35 h / 20 °C / Inert atmosphere

19.1: N-ethyl-N,N-diisopropylamine / acetone / 1 h / 0 °C / Inert atmosphere

19.2: 0.33 h / 0 °C / Inert atmosphere

20.1: toluene / 0.75 h / 80 °C / Inert atmosphere; Reflux

20.2: 5 h / 80 °C / Inert atmosphere; Reflux

21.1: N-ethyl-N,N-diisopropylamine; tetra-(n-butyl)ammonium iodide / tetrahydrofuran / 23.25 h / 0 - 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium chlorite; formic acid; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; tributylphosphine; trifluorormethanesulfonic acid; palladium 10% on activated carbon; camphor-10-sulfonic acid; diethyl methoxy borane; phenylborondichloride; hydrogen; sulfur trioxide pyridine complex; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; D-(-)-diisopropyl tartrate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; decane; hexane; dichloromethane; cyclohexane; ethyl acetate; acetone; toluene; acetonitrile; mineral oil; 3.1: |Sharpless Asymmetric Epoxidation / 4.1: |Parikh-Doering Oxidation / 5.1: |Horner-Wadsworth-Emmons Olefination / 9.1: |Sharpless Asymmetric Epoxidation / 20.2: |Curtius Rearrangement;
DOI:10.1021/jo400260m