methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Base Information

Chemical Name:methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside
CAS No.:114847-08-4
Molecular Formula:C₂₀H₂₇NO₇
Molecular Weight:393.437
Hs Code.:

Synonyms:methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Suppliers and Price of methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

There total 19 articles about methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15186-48-8
2,3-isopropylidene-glyceraldehyde

: 114847-08-4
methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 10 steps

1: 1.) 55percent NaH (in mineral oil), 2.) acetic acid / 1.) DMSO, 1.5 h, room temperature, 2.) DMSO, 20 h, room temperature

2: 45 percent / DCC / CH₂Cl₂ / 0.5 h / Ambient temperature

3: 52 percent / 1,8-diazabicyclo<5.4.0>undec-7-ene / benzene / Heating

4: 98 percent / silicagel powder, NaBH₄ / methanol / 0.25 h

5: 79 percent / H₂O, 1,8-diazabicyclo<5.4.0>undec-7-ene / pyridine / 0.75 h / Heating

6: 86 percent / Ag₂O / dimethylformamide / 4 h / Ambient temperature

7: 88 percent / LiAlH₄ / tetrahydrofuran / 5 °C

8: 48.3 percent / H₂ / 10percent Pd/C / ethanol / 5 h

9: 97 percent / triethylamine / tetrahydrofuran / 0.25 h / Ambient temperature

10: pyridine / Ambient temperature

With sodium tetrahydroborate; lithium aluminium tetrahydride; water; hydrogen; silica gel; sodium hydride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; dicyclohexyl-carbodiimide; silver(l) oxide; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1246/bcsj.62.3950

Reference yield:

: 114827-84-8
ethyl (1R,2S,5R)-6-(2,4-dimethoxybenzyl)-4,7-dioxo-2-<(1R)-1,2-isopropylidenedioxyethyl>-3-oxa-6-azabicyclo-<3.2.0>heptane-5-carboxylate

: 114847-08-4
methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / silicagel powder, NaBH₄ / methanol / 0.25 h

2: 79 percent / H₂O, 1,8-diazabicyclo<5.4.0>undec-7-ene / pyridine / 0.75 h / Heating

3: 86 percent / Ag₂O / dimethylformamide / 4 h / Ambient temperature

4: 88 percent / LiAlH₄ / tetrahydrofuran / 5 °C

5: 48.3 percent / H₂ / 10percent Pd/C / ethanol / 5 h

6: 97 percent / triethylamine / tetrahydrofuran / 0.25 h / Ambient temperature

7: pyridine / Ambient temperature

With sodium tetrahydroborate; lithium aluminium tetrahydride; water; hydrogen; silica gel; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; silver(l) oxide; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; ethanol; N,N-dimethyl-formamide;
DOI:10.1246/bcsj.62.3950

Reference yield:

: 114847-07-3
methyl 2,3-dideoxy-2-(2,4-dimethoxybenzylamino)-3-hydroxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

: 114847-08-4
methyl 2,3-dideoxy-2-benzoylamido-3-acetoxymethyl-5,6-O-isopropylidene-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 48.3 percent / H₂ / 10percent Pd/C / ethanol / 5 h

2: 97 percent / triethylamine / tetrahydrofuran / 0.25 h / Ambient temperature

3: pyridine / Ambient temperature

With hydrogen; triethylamine; palladium on activated charcoal; In tetrahydrofuran; pyridine; ethanol;
DOI:10.1246/bcsj.62.3950