{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

Base Information

Chemical Name:{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)
CAS No.:33971-07-2
Molecular Formula:C₃₈H₃₄P₂PdS₂
Molecular Weight:723.187
Hs Code.:

Synonyms:{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

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Chemical Property of {1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

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Technology Process of {1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

There total 7 articles about {1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 500128-40-5,500295-66-9
bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium

: 108-98-5
thiophenol

: 33971-07-2
{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

: 500128-43-8
(2-phenylpropyl)(SC₆H₅)[1,2-bis(diphenylphosphanyl)ethane]palladium

Guidance literature:: In tetrahydrofuran; byproducts: (CH3)2CHC6H5; to soln. of Pd(CH2CHCH3C6H5)2(dppe) in THF added C6H5SH (1:1 molar ratio) at -78°C under Ar, warmed to -30°C, stirred overnight; further C6H5SH added (final molar ratio 6:1) at -30°C until Pd complex reacted; THF removed at -30°C in vacuum, taken up in toluene, at -78°C pentane added, precipitate filtered, washed with pentane, dried at -30°C in vacuum;
DOI:10.1002/1099-0682(200211)2002:11<2868::AID-EJIC2868>3.0.CO;2-S

Reference yield: 66.0%

: 19978-61-1
(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

: 32812-89-8
bis(benzenethiolato)lead(II)

: 33971-07-2
{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

Guidance literature:: In acetone; byproducts: PbCl2; N2-atmosphere; recrystn. (Me2CO/hexane); elem. anal.;
DOI:10.1016/S0020-1693(98)00335-1

Reference yield: 45.0%

: 19978-61-1
(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

: 108-98-5
thiophenol

: 33971-07-2
{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

Guidance literature:: With N(CH₂CH₂CH₂CH₃)3; In dichloromethane; byproducts: (CH3CH2CH2CH2)3NHCl; addn. of thiophenol and N(n-C4H9)3 to a suspension of (PdCl2(Ph2PC2H4PPh2)) in CH2Cl2; stirring for 1 h;; concn.; pptn. by addn. of ethanol; the ppt. was dissolved in benzene and chromd. on alumina eluting with benzene and then CH2Cl2; the CH2Cl2 fraction was evapd. to dryness; the residue was washed with pentane and dried under vac.; elem. anal.;;