mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium

Base Information

• Chemical Name: mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium
• CAS No.: 125951-60-2
• Molecular Formula: C₄₁H₃₃NO₃PReSn
• Molecular Weight: 923.609
• Mol file: 125951-60-2.mol

Synonyms:mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium

Chemical Property of mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium

Chemical Property:

Purity/Quality:

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Technology Process of mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium

There total 5 articles about mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

trans-tetracarbonyl(triphenylphosphine)(triphenylstannyl)rhenium (125951-59-9) + trimethylamine-N-oxide (1184-78-7) → mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium (125951-60-2)

Guidance literature:

In acetonitrile; benzene; Addn. of aMe3NO soln. in CH3CN to a rapidly stirred suspn. of Re-complex in CH3CN/C6H6 under inert atmosphere, 1 h at ambient temp.; Evapn., triturating of residue with hexanes, filtn. of solid, washing (hexanes), drying in vac., elem. anal.;

DOI:10.1021/ja00163a038

Reference yield: 87.0%

fac-(acetonitrile)tricarbonylmethyl(triphenylphosphine)rhenium + Triphenyl-phenylethynyl-stannane (1247-08-1) → 1-Phenylprop-1-yne (673-32-5) + fac-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium (125951-60-2) + mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium (125951-60-2)

Guidance literature:

92 % yield of mixt. of Re-Sn-complexes, monitored by (1)H-NMR.;

DOI:10.1021/ja00163a038

Reference yield: 87.0%

fac-(acetonitrile)tricarbonylmethyl(triphenylphosphine)rhenium + Triphenyl-phenylethynyl-stannane (1247-08-1) → 1-Phenylprop-1-yne (673-32-5) + fac-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium (125951-60-2) + mer-(acetonitrile)tricarbonyl(triphenylphosphine)(triphenylstannyl)rhenium (125951-60-2)

Guidance literature:

92 % yield of mixt. of Re-Sn-complexes, monitored by (1)H-NMR.;

DOI:10.1021/ja00163a038

upstream raw materials:

Triphenyl-phenylethynyl-stannane

trans-tetracarbonyl(triphenylphosphine)(triphenylstannyl)rhenium

trimethylamine-N-oxide