2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

Base Information

Chemical Name:2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane
CAS No.:98169-87-0
Molecular Formula:C₁₉H₂₆O₃S
Molecular Weight:334.48
Hs Code.:

Synonyms:2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

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Chemical Property of 2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

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Technology Process of 2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

There total 11 articles about 2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 98127-13-0
2-<2-<1,3-dimethyl-2-<(phenylthio)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

: 98169-87-0
2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; for 2h;
DOI:10.1021/jo00221a027

Reference yield:

: 3740-59-8
3,4-dihydro-6-methyl-2H-pyran-2-one

: 98169-87-0
2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

Guidance literature:: Multi-step reaction with 10 steps

1: 1.) lithium diisopropylamide / 1.) THF, -78 deg C, 0.5 h, 2.) THF, a) -78 deg C, 4 h, b) 25 deg C, 8 h

2: 1.) CuI / 1.) THF, -20 deg C, 2.) THF, -78 deg C, 1 h

3: 1.) NaH / 1.) ether, 10 min, 2.) ether, 2 h

4: 1.) CuI / 1.) ether, -20 deg C, 2.) ether, 4 h

5: 1.) O₃, 2.) Me₂S / 1.) MeOH, CH₂Cl₂, -78 deg C, 2.) MeOH, CH₂Cl₂, 25 deg C, overnight

6: p-TsOH / benzene / 6 h / Heating

7: 98 percent / LiAlH₄ / diethyl ether / 2 h / 25 °C

8: 100 percent / N-chlorosuccinimide, Me₂S / CH₂Cl₂ / 1 h / 0 °C

9: 1.) NaH / 1.) THF, 25 deg C, 30 min, 2.) THF, 12 h

10: 96 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 2 h / -78 °C

With N-chloro-succinimide; copper(l) iodide; lithium aluminium tetrahydride; dimethylsulfide; sodium hydride; toluene-4-sulfonic acid; ozone; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00221a027

Reference yield:

: 3128-06-1
5-ketohexanoic acid

: 98169-87-0
2-<2-<1,3-dimethyl-2-<(phenylsulfinyl)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane

Guidance literature:: Multi-step reaction with 11 steps

1: 80 percent / SOCl₂ / benzene / 10 h / Heating

2: 1.) lithium diisopropylamide / 1.) THF, -78 deg C, 0.5 h, 2.) THF, a) -78 deg C, 4 h, b) 25 deg C, 8 h

3: 1.) CuI / 1.) THF, -20 deg C, 2.) THF, -78 deg C, 1 h

4: 1.) NaH / 1.) ether, 10 min, 2.) ether, 2 h

5: 1.) CuI / 1.) ether, -20 deg C, 2.) ether, 4 h

6: 1.) O₃, 2.) Me₂S / 1.) MeOH, CH₂Cl₂, -78 deg C, 2.) MeOH, CH₂Cl₂, 25 deg C, overnight

7: p-TsOH / benzene / 6 h / Heating

8: 98 percent / LiAlH₄ / diethyl ether / 2 h / 25 °C

9: 100 percent / N-chlorosuccinimide, Me₂S / CH₂Cl₂ / 1 h / 0 °C

10: 1.) NaH / 1.) THF, 25 deg C, 30 min, 2.) THF, 12 h

11: 96 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 2 h / -78 °C

With N-chloro-succinimide; copper(l) iodide; lithium aluminium tetrahydride; thionyl chloride; dimethylsulfide; sodium hydride; toluene-4-sulfonic acid; ozone; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00221a027