methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Base Information

Chemical Name:methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate
CAS No.:178244-05-8
Molecular Formula:C₂₇H₂₆O₄
Molecular Weight:416.485
Hs Code.:

Synonyms:methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Suppliers and Price of methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

There total 3 articles about methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 79-22-1
methyl chloroformate

: 178244-03-6
6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexyn-1-ol

: 178244-05-8
methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 15h; -78 deg C to room temperature;
DOI:10.1021/jo960276i

Reference yield:

: 178244-18-3
(pent-4-yn-1-yloxy)triphenylmethane

: 178244-05-8
methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 1 h, 2.) -78 deg C to room temperature, 15 h

2: 77 percent / LiAlD₄, AlCl₃ / diethyl ether; tetrahydrofuran / 0.5 h / 0 °C

3: 92 percent / DMAP, Et₃N / CH₂Cl₂ / 15 h / -78 deg C to room temperature

With dmap; n-butyllithium; aluminium trichloride; lithium aluminium deuteride; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo960276i

Reference yield:

: 178244-01-4
6-Trityloxy-hex-2-ynoic acid methyl ester

: 178244-05-8
methyl 6-[(triphenylmethyl)oxy]-1,1-dideuterio-2-hexynyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / LiAlD₄, AlCl₃ / diethyl ether; tetrahydrofuran / 0.5 h / 0 °C

2: 92 percent / DMAP, Et₃N / CH₂Cl₂ / 15 h / -78 deg C to room temperature

With dmap; aluminium trichloride; lithium aluminium deuteride; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo960276i