1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

Base Information

Chemical Name:1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene
CAS No.:226087-75-8
Molecular Formula:C₇₂H₈₆Si₂
Molecular Weight:1007.65
Hs Code.:

Synonyms:1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

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Chemical Property of 1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

Chemical Property:

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Technology Process of 1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

There total 6 articles about 1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 226087-74-7
1,4-Bis-[4-(4-bromo-phenylethynyl)-phenylethynyl]-2,5-didodecyl-benzene

: 1066-54-2
trimethylsilylacetylene

: 226087-75-8
1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; at 70 ℃;
DOI:10.1016/S0040-4039(99)00463-3

Reference yield:

: 5149-65-5
4,4'-di-n-dodecylbenzene

: 226087-75-8
1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: 93 percent / I₂, H₅IO₆, aq. AcOH, H₂SO₄ / CCl₄

2: 89 percent / bis(triphenylphosphine)palladium(II) dichloride, copper(I) iodide, triethylamine / tetrahydrofuran / 70 °C

3: 71 percent / potassium carbonate, bis(dibenzylideneacetone)palladium(O), triphenylphosphine, copper(I) iodide / tetrahydrofuran; methanol

4: 86 percent / bis(triphenylphosphine)palladium(II) dichloride, copper(I) iodide, triethylamine / tetrahydrofuran / 70 °C

5: 42 percent / potassium carbonate, bis(dibenzylideneacetone)palladium(O), triphenylphosphine, copper(I) iodide / tetrahydrofuran; methanol

6: 85 percent / bis(triphenylphosphine)palladium(II) dichloride, copper(I) iodide, triethylamine / tetrahydrofuran / 70 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; sulfuric acid; iodine; potassium carbonate; acetic acid; periodic acid; triethylamine; triphenylphosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; methanol; tetrachloromethane;
DOI:10.1016/S0040-4039(99)00463-3

Reference yield:

: 143-15-7
1-dodecylbromide

: 226087-75-8
1,4-Didodecyl-2,5-bis-[4-(4-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-benzene

Guidance literature:: Multi-step reaction with 7 steps

1: 92 percent / t-BuLi / tetrahydrofuran

2: 93 percent / I₂, H₅IO₆, aq. AcOH, H₂SO₄ / CCl₄

3: 89 percent / bis(triphenylphosphine)palladium(II) dichloride, copper(I) iodide, triethylamine / tetrahydrofuran / 70 °C

4: 71 percent / potassium carbonate, bis(dibenzylideneacetone)palladium(O), triphenylphosphine, copper(I) iodide / tetrahydrofuran; methanol

5: 86 percent / bis(triphenylphosphine)palladium(II) dichloride, copper(I) iodide, triethylamine / tetrahydrofuran / 70 °C

6: 42 percent / potassium carbonate, bis(dibenzylideneacetone)palladium(O), triphenylphosphine, copper(I) iodide / tetrahydrofuran; methanol

7: 85 percent / bis(triphenylphosphine)palladium(II) dichloride, copper(I) iodide, triethylamine / tetrahydrofuran / 70 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; sulfuric acid; iodine; tert.-butyl lithium; potassium carbonate; acetic acid; periodic acid; triethylamine; triphenylphosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; methanol; tetrachloromethane;
DOI:10.1016/S0040-4039(99)00463-3