Technology Process of C42H51NO10Si
There total 7 articles about C42H51NO10Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dmap; 2,2'-dipyridyl carbonate;
In
dichloromethane;
at 20 ℃;
for 20h;
DOI:10.1021/jo00351a008
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 94 percent / triethylamine, 4-(dimethylamino)pyridine / CH2Cl2 / 1 h
2: 1.) H2 / 1.) 10percent Pd/C / 1.) CH3OH, 15 h, 2.) CH3OH, RT, 72 h
3: 96 percent / ethyldiisopropylamine / CH2Cl2 / 40 h
4: 92 percent / potassium carbonate / methanol; H2O / 15 h
5: 61 percent / 4-(dimethylamino)pyridine, 2-dipyridyl carbonate / CH2Cl2 / 20 h / 20 °C
With
dmap; 2,2'-dipyridyl carbonate; hydrogen; potassium carbonate; triethylamine; N-ethyl-N,N-diisopropylamine;
palladium on activated charcoal;
In
methanol; dichloromethane; water;
DOI:10.1021/jo00351a008
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 90 percent / azidotrimethylsilane, zinc chloride / 48 h / 68 °C
2: 94 percent / triethylamine, 4-(dimethylamino)pyridine / CH2Cl2 / 1 h
3: 1.) H2 / 1.) 10percent Pd/C / 1.) CH3OH, 15 h, 2.) CH3OH, RT, 72 h
4: 96 percent / ethyldiisopropylamine / CH2Cl2 / 40 h
5: 92 percent / potassium carbonate / methanol; H2O / 15 h
6: 61 percent / 4-(dimethylamino)pyridine, 2-dipyridyl carbonate / CH2Cl2 / 20 h / 20 °C
With
dmap; 2,2'-dipyridyl carbonate; trimethylsilylazide; hydrogen; potassium carbonate; triethylamine; N-ethyl-N,N-diisopropylamine; zinc(II) chloride;
palladium on activated charcoal;
In
methanol; dichloromethane; water;
DOI:10.1021/jo00351a008
