fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

Base Information

Chemical Name:fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}
CAS No.:103969-95-5
Molecular Formula:C₂₀H₂₅MoN₃O₃
Molecular Weight:451.377
Hs Code.:

Synonyms:fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

Suppliers and Price of fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

There total 1 articles about fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 28227-41-0,24764-90-7
1,4-diisopropyl-1,4-diazabuta-1,3-diene

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 13939-06-5,199620-15-0
molybdenum hexacarbonyl

: 103969-95-5
fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

Guidance literature:: With CH₃CN; In acetonitrile; heating mixt. of Mo(CO)6 (11.4 mmol) and freshly distd. CH3CN at reflux for 24 h; cooling to room temp., addn. of (CH3)2CHNCHCHNCH(CH3)2 (11.5 mmol); stirring for 15 min at ambient temp.; addn. of CNC6H3(CH3)2 (11.8 mmol); stirring for 15 min;; filtering, evapg. filtrate to dryness under reduced pressure; recrystn. from acetone/petroleum ether and CH2Cl2/hexane mixts.;;
DOI:10.1016/S0277-5387(00)84447-2

Reference yield:

: 103969-95-5
fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}

: 731755-23-0
fac-{Mo(CO)3(2,6-dimethylphenyl isocyanide)(N,N'-di-iso-propylethylenediimine)}^(1-)

Guidance literature:: With Li(C₂H₅)3BH; In tetrahydrofuran; byproducts: B(C2H5)3, H2; dropwise addn. of Li(C2H5)3BH (1.0 M in THF, 0.150 mmol) to soln. of (Mo(CO)3(CNC6H3(CH3)2)((CH3)2CHNCHCHNCH(CH3)2)) (0.154 mmol) in freshly distd. THF;; not isolated from soln., identified by ESR-spectroscopy;;
DOI:10.1016/S0277-5387(00)84447-2