(r)-3-Benzyloxy-tetradecanoic acid

Base Information

• Chemical Name: (r)-3-Benzyloxy-tetradecanoic acid
• CAS No.: 87357-67-3
• Molecular Formula: C21H34 O3
• Molecular Weight: 334.499
• Hs Code.: 2918990090
• DSSTox Substance ID: DTXSID30455584
• Nikkaji Number: J1.780.549E
• Wikidata: Q82277658
• Mol file: 87357-67-3.mol

Synonyms:87357-67-3;(r)-3-benzyloxy-tetradecanoic acid;(R)-3-Benzyloxy Myristic Acid;R-(3)-Benzyloxymyristic acid;R-(3)-BENZYLOXYMYRISTICACID;(3R)-3-phenylmethoxytetradecanoic acid;(R)-3-(BENZYLOXY)TETRADECANOIC ACID;Tetradecanoic acid,3-(phenylmethoxy)-, (3R)-;(3R)-3-(Benzyloxy)tetradecanoic acid;(R)-3-BENZYLOXYTETRADECANOIC ACID;SCHEMBL1359364;R-(3)-Benzyloxy Myristic Acid;DTXSID30455584;NDCDVTWILZGAIG-HXUWFJFHSA-N

Chemical Property of (r)-3-Benzyloxy-tetradecanoic acid

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.499
• Boiling Point: 457.33°C at 760 mmHg
• Flash Point: 149.643°C
• PSA: 46.53000
• Density: 0.989g/cm³
• LogP: 5.96740
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 15
• Exact Mass: 334.25079494
• Heavy Atom Count: 24
• Complexity: 298

Purity/Quality:

99% ^*data from raw suppliers

(R)-3-BenzyloxyMyristicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCC(CC(=O)O)OCC1=CC=CC=C1
• Isomeric SMILES: CCCCCCCCCCC[C@H](CC(=O)O)OCC1=CC=CC=C1

Technology Process of (r)-3-Benzyloxy-tetradecanoic acid

There total 24 articles about (r)-3-Benzyloxy-tetradecanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(R)-3-Benzyloxytetradecanoic acid → (R)-3-benzyloxytetradecanoic acid (87357-67-3)

Guidance literature:

With potassium hydroxide; In methanol; at 35 ℃; for 1h;

Reference yield: 81.0%

phrnacyl (R)-3-(benzyloxy)tetradecanoate (87357-66-2) → (R)-3-benzyloxytetradecanoic acid (87357-67-3)

Guidance literature:

With zinc copper; acetic acid;

DOI:10.1016/S0040-4020(98)00133-1

Reference yield: 79.0%

methyl (R)-3-(benzyloxy)tetradecanoate (114264-01-6) → (R)-3-benzyloxytetradecanoic acid (87357-67-3)

Guidance literature:

With lithium hydroxide monohydrate; In tetrahydrofuran; methanol; water; acetonitrile;

upstream raw materials:

phrnacyl (R)-3-(benzyloxy)tetradecanoate

methyl (R)-3-(benzyloxy)tetradecanoate

tert-butyl (R)-3-benzyloxytetradecanoate

methyl (R)-3-hydroxytetradecanoate

Downstream raw materials:

2-acetoxyethyl 3,4,6-tri-O-acetyl-2-<(R)-3-benzyloxytetradecanoylamino>-2-deoxy-α-D-glucopyranoside

C₁₂₇H₁₉₄N₂O₁₉

(R)-3-Benzyloxy-tetradecanoic acid (2R,3R,4R,5S,6R)-2-allyloxy-5-benzyloxy-6-benzyloxymethyl-3-((R)-3-benzyloxy-tetradecanoylamino)-tetrahydro-pyran-4-yl ester

(R)-3-Benzyloxy-tetradecanoic acid (4aR,6S,7R,8R,8aS)-6-allyloxy-7-((R)-3-benzyloxy-tetradecanoylamino)-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester