2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

Base Information

Chemical Name:2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside
CAS No.:173346-43-5
Molecular Formula:C₄₂H₆₀O₇Si
Molecular Weight:705.02
Hs Code.:

Synonyms:2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

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Chemical Property of 2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

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Technology Process of 2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

There total 7 articles about 2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 173346-54-8
Acetic acid (2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((Z)-2-triisopropylsilanyloxymethyl-pent-2-enyloxy)-tetrahydro-pyran-3-yl ester

: 173346-43-5
2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With potassium carbonate; In methanol; for 16h; Yield given; Ambient temperature;

Reference yield:

: 133181-02-9,18052-21-6
3-hydroxy-2-methylene-pentanoic acid methyl ester

: 173346-43-5
2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 84 percent / Ph₃P, diethyl azodicarboxylate / tetrahydrofuran / 2 h / -40 - -30 °C

2: 87 percent / K₂CO₃ / methanol / 1 h / 0 °C

3: 2,6-lutidine / CH₂Cl₂ / 0 °C

4: DIBAL-H / hexane; CH₂Cl₂ / -78 °C

5: BF₃*OEt₂, 4A molecular sieves / CH₂Cl₂ / 4 h / -30 °C

6: K₂CO₃ / methanol / 16 h / Ambient temperature

With 2,6-dimethylpyridine; 4 A molecular sieve; boron trifluoride diethyl etherate; diisobutylaluminium hydride; potassium carbonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; hexane; dichloromethane;

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 173346-43-5
2'-<<(triisopropylsilyl)oxy>methyl>-(Z)-2'-pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 2,6-lutidine / CH₂Cl₂ / 0 °C

2: DIBAL-H / hexane; CH₂Cl₂ / -78 °C

3: BF₃*OEt₂, 4A molecular sieves / CH₂Cl₂ / 4 h / -30 °C

4: K₂CO₃ / methanol / 16 h / Ambient temperature

With 2,6-dimethylpyridine; 4 A molecular sieve; boron trifluoride diethyl etherate; diisobutylaluminium hydride; potassium carbonate; In methanol; hexane; dichloromethane;