(5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)

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Chemical Name:(5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)
CAS No.:930276-36-1
Molecular Formula:C₅₆H₄₃BrN₄Ni
Molecular Weight:910.578
Hs Code.:

Synonyms:(5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)

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Chemical Property of (5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)

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Technology Process of (5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)

There total 2 articles about (5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 156842-68-1
5,10,15,20-tetrakis(p-tolyl)-2-aza-21-carbaporphyrinato nickel(II)

: 91-13-4
α,α'-dibromo-o-xylene

: (Ni(N₄C₂₀H₇(C₆H₄CH₃)4)CH₂)2C₆H₄

: 930276-36-1
(5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)

Guidance literature:: With K₂CO₃; In ethanol; dichloromethane; Ni complex and C6H4(CH2Br)2 dissolved in CH2Cl2; suspn. of K2CO3 in EtOHadded; stirred at room temp. for 12 h in darkness; sepd. by flash chromy. (silica gel, CH2Cl2 to CH2Cl2-EtOH (5%)); crystd.from CH2Cl2-hexane;
DOI:10.1021/ic061793e

Reference yield: 57.0%

: 156842-68-1
5,10,15,20-tetrakis(p-tolyl)-2-aza-21-carbaporphyrinato nickel(II)

: 91-13-4
α,α'-dibromo-o-xylene

: 930276-36-1
(5,10,15,20-tetrakis(p-tolyl)-21-(2'-bromomethylphenylmethylene)-2-aza-21-carbaporphyrinato)nickel(II)

Guidance literature:: With K₂CO₃; dibenzo-18-crown-6; In dichloromethane; under N2; mixt. of Ni complex and C6H4(CH2Br)2 in CH2Cl2 contg. dibenzo-18-crown-6 and suspn. of K2CO3 refluxed for 2 h; solvent evapd. under reduced pressure; dissolved in CH2Cl2; sepd. by column chromy. (silica gel, CH2Cl2-EtOH (2%)); second band collected; crystd. from CH2Cl2-hexane;
DOI:10.1021/ic061793e