3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Base Information

Chemical Name:3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime
CAS No.:256469-52-0
Molecular Formula:C₁₆H₂₉NO₂Si
Molecular Weight:295.497
Hs Code.:

Synonyms:3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Suppliers and Price of 3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of 3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

There total 10 articles about 3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 256469-51-9
3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde

: 256469-52-0
3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Guidance literature:: With pyridine; hydroxylamine hydrochloride; In ethanol; at 50 ℃; for 0.0833333h;
DOI:10.1002/(SICI)1099-0690(199912)1999:12<3241::AID-EJOC3241>3.0.CO;2-9

Reference yield:

: 14782-52-6
ethylene glycole monoacetal of 2,2-dimethylcyclohexane-1,3-dione

: 256469-52-0
3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Guidance literature:: Multi-step reaction with 9 steps

1: 85 percent / LiHMDS / tetrahydrofuran / 3 h / 0 °C

2: 95 percent / LiCl; DBU / Pd(PPh₃)4 / tetrahydrofuran / 20 °C / Heating

3: 100 percent / 9-BBN; H₂O₂; NaOH / tetrahydrofuran; ethanol / 3 h / Heating

4: 100 percent / CBr₄; PPh₃ / CH₂Cl₂ / 1 h / 0 °C

5: 95 percent / CuI / tetrahydrofuran / 1 h / 0 - 20 °C

6: 100 percent / p-TsOH / acetone; H₂O / 5 h / Heating

7: 85 percent / ZnI₂ / CH₂Cl₂ / 0 - 20 °C

8: 70 percent / diisobutylaluminium hydride / toluene; diethyl ether / 2 h / 0 °C

9: 95 percent / hydroxylamine hydrochloride; pyridine / ethanol / 0.08 h / 50 °C

With pyridine; sodium hydroxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; carbon tetrabromide; hydroxylamine hydrochloride; dihydrogen peroxide; diisobutylaluminium hydride; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine; lithium chloride; zinc(II) iodide; lithium hexamethyldisilazane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water; acetone; toluene; 1: Substitution / 2: Substitution / 3: hydroboration / 4: Bromination / 5: Substitution / 6: dioxolan cleavage / 7: Addition / 8: Reduction / 9: Condensation;
DOI:10.1002/(SICI)1099-0690(199912)1999:12<3241::AID-EJOC3241>3.0.CO;2-9

Reference yield:

: 256469-23-5
6,6-dimethyl-1,4-dioxaspiro[4.5]dec-7-en-7-yl trifluoromethanesulfonate

: 256469-52-0
3-but-3-enyl-2,2-dimethyl-1-trimethylsilanyloxy-cyclohex-3-enecarbaldehyde oxime

Guidance literature:: Multi-step reaction with 8 steps

1: 95 percent / LiCl; DBU / Pd(PPh₃)4 / tetrahydrofuran / 20 °C / Heating

2: 100 percent / 9-BBN; H₂O₂; NaOH / tetrahydrofuran; ethanol / 3 h / Heating

3: 100 percent / CBr₄; PPh₃ / CH₂Cl₂ / 1 h / 0 °C

4: 95 percent / CuI / tetrahydrofuran / 1 h / 0 - 20 °C

5: 100 percent / p-TsOH / acetone; H₂O / 5 h / Heating

6: 85 percent / ZnI₂ / CH₂Cl₂ / 0 - 20 °C

7: 70 percent / diisobutylaluminium hydride / toluene; diethyl ether / 2 h / 0 °C

8: 95 percent / hydroxylamine hydrochloride; pyridine / ethanol / 0.08 h / 50 °C

With pyridine; sodium hydroxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; carbon tetrabromide; hydroxylamine hydrochloride; dihydrogen peroxide; diisobutylaluminium hydride; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine; lithium chloride; zinc(II) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water; acetone; toluene; 1: Substitution / 2: hydroboration / 3: Bromination / 4: Substitution / 5: dioxolan cleavage / 6: Addition / 7: Reduction / 8: Condensation;
DOI:10.1002/(SICI)1099-0690(199912)1999:12<3241::AID-EJOC3241>3.0.CO;2-9