benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

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Chemical Name:benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester
CAS No.:926315-15-3
Molecular Formula:C₂₂H₃₁FO₃Si
Molecular Weight:390.57
Hs Code.:

Synonyms:benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

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Chemical Property of benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

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Technology Process of benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

There total 10 articles about benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 926315-14-2
benzoic acid (2R,3S,5S,7R)-[7-(t-butyldimethyl)silanyloxy-5-fluoro-4-methylene-1-oxa-spiro[2.5]oct-2-yl] methyl ester

: 926315-15-3
benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

Guidance literature:: With triphenylphosphine; In toluene; at 100 ℃; for 14h;

Reference yield:

: 926315-12-0
benzoic acid (2R,3S,7S)-7-((t-butyldimethyl)silanyloxy)-4-methylene-1-oxa-spiro[2.5]oct-2-yl methyl ester

: 926315-15-3
benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: tert.-butylhydroperoxide; selenium(IV) oxide / 1,4-dioxane; nonane / 22 h / 85 °C

2.1: diethylamino-sulfur trifluoride / Trichloroethylene / 0.33 h / -75 °C

2.2: -75 °C

3.1: triphenylphosphine / toluene / 20 h / 100 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; diethylamino-sulfur trifluoride; triphenylphosphine; In 1,4-dioxane; nonane; Trichloroethylene; toluene;

Reference yield:

: t-butyl-dimethyl-(4-methylene-3-{2-[7a-methyl-1-(1,4,5-trimethyl-hex-2-enyl)-octahydro-inden-4-ylidene]-ethylidene}-cyclohexyloxy)-silane

: 926315-15-3
benzoic acid 2-[(3S,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-fluoro-2-methylene-cyclohex-(Z)-ylidene]-ethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: pyridine; N-ethyl-1-[{4-(phenylazo)-phenyl}-azo]-2-naphthalenylamine; ozone / dichloromethane / 0.92 h / -60 - -55 °C

1.2: 1 h / 20 °C

2.1: sodium acetate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / 10 - 20 °C

3.1: pyridine / 1 h / 20 °C

3.2: 0.75 h / 20 °C

4.1: tert.-butylhydroperoxide; selenium(IV) oxide / 1,4-dioxane; nonane / 22 h / 85 °C

5.1: diethylamino-sulfur trifluoride / Trichloroethylene / 0.33 h / -75 °C

5.2: -75 °C

6.1: triphenylphosphine / toluene / 20 h / 100 °C

With pyridine; tert.-butylhydroperoxide; selenium(IV) oxide; diethylamino-sulfur trifluoride; N-ethyl-1-[{4-(phenylazo)-phenyl}-azo]-2-naphthalenylamine; sodium acetate; ozone; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In 1,4-dioxane; pyridine; nonane; dichloromethane; Trichloroethylene; toluene;