methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside

Base Information

• Chemical Name: methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside
• CAS No.: 1257791-14-2
• Molecular Formula: C₇₁H₇₁NO₁₈
• Molecular Weight: 1226.34
• Mol file: 1257791-14-2.mol

Synonyms:methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside

Chemical Property of methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside

There total 1 articles about methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylohexopyranosyl)-(1->4)-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside (1257791-13-1) + ethyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside (116514-50-2,128962-63-0,131545-02-3,136758-06-0,99409-34-4,116391-11-8) → methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside (1257791-14-2)

Guidance literature:

With N-iodo-succinimide; trifluorormethanesulfonic acid; In toluene; at -30 ℃; for 1h; stereoselective reaction; Inert atmosphere; Molecular sieve;

DOI:10.1007/s11426-010-4060-6

Reference yield:

methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside (1257791-14-2) + acetic anhydride (108-24-7) → C49H61NO14

Guidance literature:

methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylo-hexopyranosyl)-(1->4)-[2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)]-6-O-benzyl-2-deoxy-2-phthalimido-β-Dglucopyranoside; With water; hydrazine hydrate; In ethanol; for 15h; Reflux;

acetic anhydride; In methanol; dichloromethane; at 20 ℃; for 15h;

DOI:10.1007/s11426-010-4060-6

upstream raw materials:

methyl (4-O-acetyl-2,6-di-O-benzoyl-3-deoxy-β-D-xylohexopyranosyl)-(1->4)-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

ethyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside