4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole

Base Information

• Chemical Name: 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole
• CAS No.: 1361000-47-6
• Molecular Formula: C₄₀H₃₆BrN₃S₃
• Molecular Weight: 734.848
• Mol file: 1361000-47-6.mol

Synonyms:4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole

Chemical Property of 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole

There total 6 articles about 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(4-hexyl-2-thienyl)-2,1,3-benzothiadiazole (1361000-44-3) → 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole (1361000-47-6)

Guidance literature:

With N-Bromosuccinimide; acetic acid; In chloroform; at 20 ℃; Inert atmosphere; Darkness; Cooling with ice;

DOI:10.1002/chem.201102598

Reference yield:

4-(2-(tributylstannyl)thiophene-5-yl)-N,N-bis(4-methylphenyl)aniline (1374310-76-5) → 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole (1361000-47-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 24 h / Inert atmosphere; Reflux

2: N-Bromosuccinimide; acetic acid / chloroform / 20 °C / Inert atmosphere; Darkness; Cooling with ice

With N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; acetic acid; In chloroform; toluene; 1: Stille coupling;

DOI:10.1002/chem.201102598

Reference yield:

4-bromo-7-(4-hexylthiophen-2-yl)benzo[c][1,2,5]thiadiazole (1192689-61-4) → 4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(5-bromo-4-hexyl-2-thienyl)-2,1,3-benzothiadiazole (1361000-47-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 24 h / Inert atmosphere; Reflux

2: N-Bromosuccinimide; acetic acid / chloroform / 20 °C / Inert atmosphere; Darkness; Cooling with ice

With N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; acetic acid; In chloroform; toluene; 1: Stille coupling;

DOI:10.1002/chem.201102598

upstream raw materials:

4-bromo-7-(4-hexylthiophen-2-yl)benzo[c][1,2,5]thiadiazole

4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(4-hexyl-2-thienyl)-2,1,3-benzothiadiazole

4-(2-(tributylstannyl)thiophene-5-yl)-N,N-bis(4-methylphenyl)aniline

4-tolyl iodide

Downstream raw materials:

4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(4-hexyl-5-ethynyl-2-thienyl)-2,1,3-benzothiadiazole

4-(5-(N,N-di-p-tolyl-4-aminophenyl)-thiophen-2-yl)-7-(4-hexyl-5-(trimethylsilylethynyl)-2-thienyl)-2,1,3-benzothiadiazole