S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate

Base Information

Chemical Name:S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate
CAS No.:155626-85-0
Molecular Formula:C₂₁H₂₅NOS₂
Molecular Weight:371.568
Hs Code.:

Synonyms:S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate

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Chemical Property of S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate

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Technology Process of S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate

There total 2 articles about S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 120205-96-1,121010-18-2,129286-74-4,111060-63-0
(S)-2-(dibenzylamino)propanal

: 155626-85-0
S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium tert-butylate / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

1.2: -78 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.67 h / -78 °C / Inert atmosphere

2.2: -78 - 20 °C

3.1: sodium hexamethyldisilazane / tetrahydrofuran / 0 °C / Inert atmosphere

3.2: 0 - 20 °C / Inert atmosphere

3.3: 2 h / 20 °C / Inert atmosphere

With potassium tert-butylate; sodium hexamethyldisilazane; diisobutylaluminium hydride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1016/j.tet.2012.05.032

Reference yield:

: 123725-86-0
ethyl (4S,2E)-4-(N,N-dibenzylamino)pent-2-enoate

: 155626-85-0
S-methyl O-[(4S,2E)-4-(N,N-dibenzylamino)pent-2-en-1-yl] dithiocarbonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.67 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C

2.1: sodium hexamethyldisilazane / tetrahydrofuran / 0 °C / Inert atmosphere

2.2: 0 - 20 °C / Inert atmosphere

2.3: 2 h / 20 °C / Inert atmosphere

With sodium hexamethyldisilazane; diisobutylaluminium hydride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1016/j.tet.2012.05.032