Ethyl-3-cyclopropyl-3-phenyl-2-propenoat

Base Information

• Chemical Name: Ethyl-3-cyclopropyl-3-phenyl-2-propenoat
• CAS No.: 26482-38-2
• Molecular Formula: C₁₄H₁₆O₂
• Molecular Weight: 216.28
• Mol file: 26482-38-2.mol

Synonyms:Ethyl-3-cyclopropyl-3-phenyl-2-propenoat

Chemical Property of Ethyl-3-cyclopropyl-3-phenyl-2-propenoat

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ethyl-3-cyclopropyl-3-phenyl-2-propenoat

There total 2 articles about Ethyl-3-cyclopropyl-3-phenyl-2-propenoat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethoxyphosphoryl-acetic acid ethyl ester (867-13-0) + cyclopropyl phenyl ketone (3481-02-5) → Ethyl-3-cyclopropyl-3-phenyl-2-propenoat (26482-38-2)

Guidance literature:

diethoxyphosphoryl-acetic acid ethyl ester; With sodium hydride; In tetrahydrofuran; at 23 ℃; for 0.5h;

cyclopropyl phenyl ketone; In tetrahydrofuran; at 23 ℃; for 12h;

DOI:10.1021/jacs.0c00147

Reference yield:

→ Ethyl-3-cyclopropyl-3-phenyl-2-propenoat (26482-38-2)

Guidance literature:

Cyclopropylphenylketon, Triethylphosphonoacetat;

DOI:10.1002/hlca.19770600334

Reference yield: 85.0%

Ethyl-3-cyclopropyl-3-phenyl-2-propenoat (26482-38-2) → (2Z,4E)-3-Phenyl-hexa-2,4-dienoic acid ethyl ester

Guidance literature:

With iron pentacarbonyl; In diethylene glycol dimethyl ether; at 150 ℃; Mechanism; selective isomerization;

DOI:10.1016/0040-4039(95)02204-X

upstream raw materials:

diethoxyphosphoryl-acetic acid ethyl ester

cyclopropyl phenyl ketone

Downstream raw materials:

(Z)-3-Cyclopropyl-3-phenyl-prop-2-en-1-ol