3-deuterio-5-tert-butyl-2-cyclohexenone

Base Information

Chemical Name:3-deuterio-5-tert-butyl-2-cyclohexenone
CAS No.:197657-53-7
Molecular Formula:C₁₀H₁₆O
Molecular Weight:153.228
Hs Code.:

Synonyms:3-deuterio-5-tert-butyl-2-cyclohexenone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-deuterio-5-tert-butyl-2-cyclohexenone

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Technology Process of 3-deuterio-5-tert-butyl-2-cyclohexenone

There total 2 articles about 3-deuterio-5-tert-butyl-2-cyclohexenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5-tert-butyl-3-isobutoxy-cyclohex-2-enone

: 197657-53-7
3-deuterio-5-tert-butyl-2-cyclohexenone

Guidance literature:: 5-tert-butyl-3-isobutoxy-cyclohex-2-enone; With lithium aluminium deuteride; In diethyl ether; at 0 ℃; for 1h;

With hydrogenchloride; In diethyl ether; water;
DOI:10.1021/jo9615155

Reference yield:

: 49673-64-5
5-tert-butylcyclohexane-1,3-dione

: 197657-53-7
3-deuterio-5-tert-butyl-2-cyclohexenone

Guidance literature:: Multi-step reaction with 2 steps

1.1: p-toluenesulfonic acid / benzene / Heating

2.1: LiAlD₄ / diethyl ether / 1 h / 0 °C

2.2: aq. HCl / diethyl ether; H₂O

With lithium aluminium deuteride; toluene-4-sulfonic acid; In diethyl ether; benzene; 1.1: Condensation / 2.1: Reduction / 2.2: Hydrolysis;
DOI:10.1021/jo9615155

Reference yield:

: 197657-53-7
3-deuterio-5-tert-butyl-2-cyclohexenone

: cis-1-deuterio-5-tert-butyl-2-cyclohexen-1-ol

: trans-1-deuterio-5-tert-butyl-2-cyclohexen-1-ol

Guidance literature:: 3-deuterio-5-tert-butyl-2-cyclohexenone; With sodium hydroxide; dihydrogen peroxide; In methanol; at 0 - 20 ℃;

With sodium hydroxide; hydrazine hydrate; In methanol; at 0 - 20 ℃; for 2h; Title compound not separated from byproducts;
DOI:10.1021/jo9615155