{tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl₂

Base Information

• Chemical Name: {tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl₂
• CAS No.: 31790-57-5
• Molecular Formula: C₆₆H₄₈N₆Ru*2Cl
• Molecular Weight: 1097.12
• Mol file: 31790-57-5.mol

Synonyms:{tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl₂

Chemical Property of {tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl₂

There total 1 articles about {tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichlorotetrakis(dimethylsulfoxide)ruthenium (59091-96-2,89395-66-4,90698-13-8,194497-67-1,482618-33-7,41290-68-0,72904-47-3,61779-29-1,64376-67-6,75766-08-4) + 4,4'-diphenyl-2,2'-bipyridine (6153-92-0) → {tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl2 (31790-57-5)

Guidance literature:

In ethanol; refluxing Ru complex with an excess amt. of ligand; washing crude salts with cold water, then with Et2O; drying (vac.); recrystn. from water;

DOI:10.1021/j100367a040

Reference yield:

{tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl2 (31790-57-5) → 4,4'-diphenyl-2,2'-bipyridine (6153-92-0)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); photolysis (He-Cd laser, 442 nm, room temp.); HPLC anal., estimation of quantum yield;

Reference yield:

ammonium hexafluorophosphate + {tris(4,4'-diphenyl-2,2'-bipyridine)ruthenium(II)}Cl2 (31790-57-5) → tris(4,4'-diphenyl-2,2'bbipyridine)ruthenium(II) hexafluorophosphate (123148-14-1)

Guidance literature:

In water; exchanging counteranions; washing crude salts with cold water, then with Et2O; drying (vac.); chromy. (alumina);

DOI:10.1021/j100367a040

upstream raw materials:

dichlorotetrakis(dimethylsulfoxide)ruthenium

4,4'-diphenyl-2,2'-bipyridine

Downstream raw materials:

4,4'-diphenyl-2,2'-bipyridine

tris(4,4'-diphenyl-2,2'bbipyridine)ruthenium(II) hexafluorophosphate