3-Tosyl-2,2-dinitropropyl allyl ether

Base Information

• Chemical Name: 3-Tosyl-2,2-dinitropropyl allyl ether
• CAS No.: 76828-32-5
• Molecular Formula: C₁₃H₁₆N₂O₈S
• Molecular Weight: 360.345
• Mol file: 76828-32-5.mol

Synonyms:3-Tosyl-2,2-dinitropropyl allyl ether

Chemical Property of 3-Tosyl-2,2-dinitropropyl allyl ether

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-Tosyl-2,2-dinitropropyl allyl ether

There total 2 articles about 3-Tosyl-2,2-dinitropropyl allyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

3-Hydroxy-2,2-dinitropropyl allyl ether (76828-30-3) + p-toluenesulfonyl chloride (98-59-9) → 3-Tosyl-2,2-dinitropropyl allyl ether (76828-32-5)

Guidance literature:

With pyridine N-oxide; In chloroform; for 114h; Heating;

DOI:10.1021/je00024a039

Reference yield:

Potassium 2,2-dinitroethyl allyl ether → 3-Tosyl-2,2-dinitropropyl allyl ether (76828-32-5)

Guidance literature:

Multi-step reaction with 2 steps

1: glacial acetic acid / H₂O / 1 h / Ambient temperature

2: pyridine N-oxide / CCl₄ / 96 h / 60 °C

With pyridine N-oxide; acetic acid; In tetrachloromethane; water;

DOI:10.1021/je00027a030

Reference yield: 97.0%

3-Tosyl-2,2-dinitropropyl allyl ether (76828-32-5) → 3-tosyl-2,2-dinitropropyl 2,3-dibromopropyl ether (79795-22-5)

Guidance literature:

With bromine; In tetrachloromethane; 1.) 0 deg C, 30 min, 2.) ambient temp., 16 h;

DOI:10.1021/je00027a030

upstream raw materials:

3-Hydroxy-2,2-dinitropropyl allyl ether

p-toluenesulfonyl chloride

Downstream raw materials:

3-tosyl-2,2-dinitropropyl 2,3-dibromopropyl ether

Refernces

• 1、 Frankel,Wilson. "ENERGETIC AZIDO MONOMERS.". . p. 219. Retrieved 1981.