(R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal

Base Information

• Chemical Name: (R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal
• CAS No.: 1072831-29-8
• Molecular Formula: C₂₀H₂₄O₅S₂
• Molecular Weight: 408.54
• Mol file: 1072831-29-8.mol

Synonyms:(R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal

Chemical Property of (R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal

Chemical Property:

Purity/Quality:

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Technology Process of (R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal

There total 1 articles about (R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,1-bis(phenylsulfonyl)ethylene (39082-53-6) + hexanal (66-25-1) → (R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal (1072831-29-8) + (S)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal

Guidance literature:

With (S)-N-(3,5-bis(trifluoromethyl)phenyl)-2-(diphenyl ((tri-methylsilyl)oxy)methyl)pyrrolidine-1-carbothioamide; benzoic acid; In dichloromethane; water; at 20 ℃; for 18h; enantioselective reaction;

DOI:10.1039/c6ob00387g

Reference yield:

(R)-2-[2,2-bis(phenylsulphonyl)ethyl]hexanal (1072831-29-8) → C20H26O5S2

Guidance literature:

With sodium tetrahydroborate; ethanol; In chloroform-d1; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/anie.201908330

upstream raw materials:

1,1-bis(phenylsulfonyl)ethylene

hexanal