oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde

Base Information

• Chemical Name: oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde
• CAS No.: 73661-48-0
• Molecular Formula: C₁₀H₁₇NO
• Molecular Weight: 167.251
• Mol file: 73661-48-0.mol

Synonyms:oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde

Chemical Property of oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde

There total 1 articles about oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2,6,6-trimethylcyclohex-1-enecarbaldehyde (432-25-7) → oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde (73661-48-0)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; In ethanol; Reflux;

DOI:10.1080/14786419.2018.1548456

Reference yield: 91.0%

oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde (73661-48-0) → 2,6,6-trimethylcyclohex-1-enecarbaldehyde (432-25-7)

Guidance literature:

With manganese(IV) oxide; In hexane; for 0.25h;

DOI:10.1016/00404-0399(50)1356-M

Reference yield:

oxime 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde (73661-48-0) → 5-amino-3-(2,6,6-trimethyl-cyclohex-1-enyl)-isoxazole-4-carbonitrile (19206-28-1)

Guidance literature:

Multi-step reaction with 2 steps

1: NBS, NaOEt

2: NaOMe / methanol / 0.25 h / Heating

With N-Bromosuccinimide; sodium methylate; sodium ethanolate; In methanol;

DOI:10.1021/jo01258a125

upstream raw materials:

2,6,6-trimethylcyclohex-1-enecarbaldehyde

Downstream raw materials:

2,2,6-trimethyl-1-cyclohexenylcarbonitrile

(2,6,6-Trimethylcyclohexenyl)nitriloxid

2,6,6-trimethylcyclohex-1-enecarbaldehyde

5-amino-3-(2,6,6-trimethyl-cyclohex-1-enyl)-isoxazole-4-carbonitrile

Refernces