methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside

Base Information

• Chemical Name: methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside
• CAS No.: 1096035-28-7
• Molecular Formula: C₁₆H₂₃NO₅
• Molecular Weight: 309.362
• Mol file: 1096035-28-7.mol

Synonyms:methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside

Chemical Property of methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside

There total 1 articles about methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

methyl 2-acetamido-3-O-benzyl-2-deoxy-6-O-methanesulfonyl-β-D-glucopyranoside (142488-29-7) → methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside (1096035-28-7)

Guidance literature:

With sodium tetrahydroborate; In dimethyl sulfoxide; at 85 - 90 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jo801927k

Reference yield: 87.0%

methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside (1096035-28-7) → methyl 4-azido-3-O-benzyl-2,4,6-trideoxy-2-(1H-5-methyltetrazol-1-yl)-β-D-galactopyranoside (1096035-30-1)

Guidance literature:

methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside; With pyridine; trifluoromethylsulfonic anhydride; In dichloromethane; at -10 ℃; for 3h; Inert atmosphere;

With sodium azide; In N,N-dimethyl-formamide; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jo801927k

Reference yield: 66.0%

methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside (1096035-28-7) → methyl 2-acetamido-4-azido-3-O-benzyl-2,4,6-trideoxy-β-D-galactopyranoside (1096035-34-5)

Guidance literature:

methyl 2-acetamido-3-O-benzyl-2,6-dideoxy-β-D-glucopyranoside; With pyridine; trifluoromethylsulfonic anhydride; In dichloromethane; at -30 ℃; for 3h; Inert atmosphere;

With sodium azide; In N,N-dimethyl-formamide; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jo801927k

upstream raw materials:

methyl 2-acetamido-3-O-benzyl-2-deoxy-6-O-methanesulfonyl-β-D-glucopyranoside

Downstream raw materials:

methyl 4-azido-3-O-benzyl-2,4,6-trideoxy-2-(1H-5-methyltetrazol-1-yl)-β-D-galactopyranoside

methyl 2-acetamido-4-azido-3-O-benzyl-2,4,6-trideoxy-β-D-galactopyranoside