Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

Base Information

Chemical Name:Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester
CAS No.:133407-53-1
Molecular Formula:C₂₄H₄₂O₅SSi
Molecular Weight:470.746
Hs Code.:

Synonyms:Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

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Chemical Property of Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

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Technology Process of Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

There total 7 articles about Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: Toluene-4-sulfonic acid (1R,3R,4R)-4-hydroxy-3-methoxy-cyclohexylmethyl ester

: 133407-53-1
Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

Guidance literature:: With 2,6-dimethylpyridine; at 0 ℃;
DOI:10.1016/S0040-4039(00)79493-7

Reference yield:

: 109466-73-1
(-)-(1R,2R,4R)-4-hydroxymethyl-2-methoxycyclohexan-1-ol

: 133407-53-1
Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / pyridine / CH₂Cl₂

2: 95 percent / 2,6-lutidine / 0 °C

With pyridine; 2,6-dimethylpyridine; In dichloromethane;
DOI:10.1016/S0040-4039(00)79493-7

Reference yield:

: 133407-52-0
(1R,4R,5R)-4-benzoyloxy-6-oxabicyclo[3.2.1]octan-7-one

: 133407-53-1
Toluene-4-sulfonic acid (1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexylmethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 85 percent / K₂CO₃ / 0.08 h / 0 °C

2: 89 percent / 2,4,6-tri-t-butylpyridine / CHCl₃

3: 84 percent / LiAlH₄ / diethyl ether / Ambient temperature

4: 75 percent / pyridine / CH₂Cl₂

5: 95 percent / 2,6-lutidine / 0 °C

With pyridine; 2,6-dimethylpyridine; lithium aluminium tetrahydride; 2,4,6-tri-tertbutylpyridine; potassium carbonate; In diethyl ether; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)79493-7