chlorure de l'acide tri-O-acetylshikimique

Base Information

• Chemical Name: chlorure de l'acide tri-O-acetylshikimique
• CAS No.: 501433-74-5
• Molecular Formula: C₁₃H₁₅ClO₇
• Molecular Weight: 318.711
• Mol file: 501433-74-5.mol

Synonyms:chlorure de l'acide tri-O-acetylshikimique

Chemical Property of chlorure de l'acide tri-O-acetylshikimique

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of chlorure de l'acide tri-O-acetylshikimique

There total 1 articles about chlorure de l'acide tri-O-acetylshikimique which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(3R,4S,5R)-3,4,5-triacetoxycyclohex-1-ene-1-carboxylic acid (98167-08-9) → chlorure de l'acide tri-O-acetylshikimique (501433-74-5)

Guidance literature:

With thionyl chloride; In chloroform; for 2h; Heating;

Reference yield: 72.5%

chlorure de l'acide tri-O-acetylshikimique (501433-74-5) + phenylboronic acid (98-80-6) → (1R,2S,3R)-5-benzoylcyclohex-4-ene-1,2,3-triyl triacetate

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium phosphate tribasic trihydrate; In toluene; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1039/c3ra43755h

Reference yield: 72.0%

4-methylphenylboronic acid (5720-05-8) + chlorure de l'acide tri-O-acetylshikimique (501433-74-5) → (1R,2S,3R)-5-(4-methylbenzoyl)cyclohex-4-ene-1,2,3-triyl triacetate

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium phosphate tribasic trihydrate; In toluene; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1039/c3ra43755h

upstream raw materials:

(3R,4S,5R)-3,4,5-triacetoxycyclohex-1-ene-1-carboxylic acid

Downstream raw materials:

((3R)-3r,4c,5t-triacetoxy-cyclohex-1-enyl)-methanol

(3R)-3r,4c,5t-triacetoxy-cyclohex-1-enecarbaldehyde

ent-11,17β-dimethoxy-18α-((3S)-3r,4c,5t-triacetoxy-cyclohex-1-enecarbonyloxy)-15β-yohimban-16α-carboxylic acid methyl ester

(3,4,5-tri-O-acetylshikimyl)acetate de tert-butyle