(bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene)

Base Information

• Chemical Name: (bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene)
• CAS No.: 946090-30-8
• Molecular Formula: C₃₃H₅₁FP₂Pt
• Molecular Weight: 723.794
• Mol file: 946090-30-8.mol

Synonyms:(bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene)

Chemical Property of (bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene)

There total 2 articles about (bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

bis(cycloocta-1,5-diene)platinum(0) (12130-66-4) + 1-(4-fluorophenyl)-2-(4-methylphenyl)acetylene (64583-17-1) + 1,2-bis(di-tert-butyl)phosphinoethane (4141-59-7,107783-62-0) → (bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene) (946090-30-8)

Guidance literature:

In benzene-d6; under N2 atm. soln. acetylene in C6D6 was added to Pt complex, mixt. wasstirred for 10 s, soln. ligand in C6D6 was added, mixt. was stirred for 3 min and heated at 100°C for 1 day; mixt. was evapd. in vac., solid was redissolved in C6H6, crystd. at roomtemp. via solvent evapn. for 3 days; elem. anal.;

DOI:10.1021/ja071698k

Reference yield:

(bis(di-t-butylphosphino)ethane)Pt(p-tolyl)(p-fluorophenylacetylide) (946090-32-0) + (bis(di-t-butylphosphino)ethane)Pt(p-fluorophenyl)(p-tolylacetylide) (946090-31-9) → (bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene) (946090-30-8)

Guidance literature:

In not given; heating at 100°C; Kinetics;

DOI:10.1021/ja071698k

Reference yield:

(bis(di-t-butylphosphino)ethane)Pt(η2-(p-fluorophenyl-p-tolyl)acetylene) (946090-30-8) → (bis(di-t-butylphosphino)ethane)Pt(p-tolyl)(p-fluorophenylacetylide) (946090-32-0) + (bis(di-t-butylphosphino)ethane)Pt(p-fluorophenyl)(p-tolylacetylide) (946090-31-9)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); under N2 atm. soln. Pt complex in C6D6 was irradiated with UV light (> 300 nm) upon overnight; crystd. at room temp. via solvent evapn. for 4 days;

DOI:10.1021/ja071698k

upstream raw materials:

bis(cycloocta-1,5-diene)platinum⁽⁰⁾

1-(4-fluorophenyl)-2-(4-methylphenyl)acetylene

1,2-bis(di-tert-butyl)phosphinoethane

(bis(di-t-butylphosphino)ethane)Pt(p-tolyl)(p-fluorophenylacetylide)

Downstream raw materials:

(bis(di-t-butylphosphino)ethane)Pt(p-tolyl)(p-fluorophenylacetylide)

(bis(di-t-butylphosphino)ethane)Pt(p-fluorophenyl)(p-tolylacetylide)

Refernces