{3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

Base Information

Chemical Name:{3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane
CAS No.:874331-83-6
Molecular Formula:C₄₇H₆₅BrO₂Si
Molecular Weight:770.021
Hs Code.:

Synonyms:{3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

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Chemical Property of {3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

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Technology Process of {3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

There total 9 articles about {3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 874331-82-5
{3-[4-(3-ethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

: 874331-83-6
{3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

Guidance literature:: With N-Bromosuccinimide; silver nitrate; In acetone; at 20 ℃; for 1h;
DOI:10.1021/jo051969e

Reference yield:

: 874331-77-8
1-bromo-3-iodo-5-(octyloxymethyl)benzene

: 874331-83-6
{3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 8.49 g / Pd₂(dba)3*CHCl₃; CuI; Et₃N / PPh₃ / 24 h / 50 °C

2: 96 percent / Pd₂(dba)3*CHCl₃; CuI; Et₃N / PPh₃ / 24 h / 75 °C

3: 96 percent / K₂CO₃ / tetrahydrofuran; methanol / 1.5 h / 20 °C

4: 99 percent / N-bromosuccinimide; AgNO₃ / acetone / 1 h / 20 °C

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; N-Bromosuccinimide; copper(l) iodide; potassium carbonate; silver nitrate; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; acetone;
DOI:10.1021/jo051969e

Reference yield:

: 111-83-1
1-bromo-octane

: 874331-83-6
{3-[4-(3-bromoethynyl-5-octyloxymethyl-phenyl)-buta-1,3-diynyl]-5-octyloxymethyl-phenylethynyl}-triisopropyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 77 percent / t-BuOK; 18-crown-6 / tetrahydrofuran / 24 h / Heating

2: 8.49 g / Pd₂(dba)3*CHCl₃; CuI; Et₃N / PPh₃ / 24 h / 50 °C

3: 96 percent / Pd₂(dba)3*CHCl₃; CuI; Et₃N / PPh₃ / 24 h / 75 °C

4: 96 percent / K₂CO₃ / tetrahydrofuran; methanol / 1.5 h / 20 °C

5: 99 percent / N-bromosuccinimide; AgNO₃ / acetone / 1 h / 20 °C

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; N-Bromosuccinimide; copper(l) iodide; 18-crown-6 ether; potassium tert-butylate; potassium carbonate; silver nitrate; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; acetone;
DOI:10.1021/jo051969e