[η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh)

Base Information

• Chemical Name: [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh)
• CAS No.: 207725-37-9
• Molecular Formula: C₄₀H₂₇MoO₃P
• Molecular Weight: 682.566
• Mol file: 207725-37-9.mol

Synonyms:[η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh)

Chemical Property of [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh)

There total 5 articles about [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

[η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum iodide (184951-23-3) + tributylstannylethynylbenzene (3757-88-8) → [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh) (207725-37-9)

Guidance literature:

dichloro bis(acetonitrile) palladium(II); 5% of catalyst;

DOI:10.1021/om980167p

Reference yield:

[η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum-Pd(PPh3)(C*CPh) → bis[1,2-bis(diphenylphosphino)ethane]palladium(0) (31277-98-2) + [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh) (207725-37-9)

Guidance literature:

With 1,2-bis-(diphenylphosphino)ethane; In d₇-N,N-dimethylformamide; byproducts: PPh3; not sepd.; NMR spectroscopy;

DOI:10.1021/om980167p

Reference yield:

[(η5-(1-Ph2P-2,4-Ph2)C5H2)(CO)3MoPd(μ-I)2PdMo(CO)3(η5-(1-Ph2P-2,4-Ph2)C5H2)] + tributylstannylethynylbenzene (3757-88-8) → [η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum(C*CPh) (207725-37-9)

Guidance literature:

With DMF; In N,N-dimethyl-formamide; (Ar); using Schlenk techniques; dissolving of (((Ph2P)(Ph)2C5H2)Mo(CO)3PdI)2 in DMF, addn. of 8-fold excess of Bu3SnCCPh, warming overnight at 60°C; monitoring by NMR;

DOI:10.1021/ja011644p

upstream raw materials:

[η(5)-1-(diphenylphosphino)-2,4-diphenylcyclopentadienyl]tricarbonylmolybdenum iodide

tributylstannylethynylbenzene