BROMO(PHENYL-D5)MAGNESIUM

Base Information

• Chemical Name: BROMO(PHENYL-D5)MAGNESIUM
• CAS No.: 84783-81-3
• Molecular Formula: C6Br D5 Mg
• Molecular Weight: 186.275
• Mol file: 84783-81-3.mol

Synonyms:Benzene-d5,magnesium complex; Bromo(phenyl-d5)magnesium; Perdeuteriophenylmagnesiumbromide

Chemical Property of BROMO(PHENYL-D5)MAGNESIUM

Chemical Property:

• PSA: 0.00000
• Density: 0.792
• LogP: 2.33240

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BROMO(PHENYL-D5)MAGNESIUM

There total 2 articles about BROMO(PHENYL-D5)MAGNESIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromobenzene-d5 (4165-57-5) → phenylmagnesium bromide-d5 (84783-81-3)

Guidance literature:

With magnesium; In tetrahydrofuran; for 0.5h; Heating;

DOI:10.1039/P29880000403

Reference yield:

bromobenzene-d5 (4165-57-5) → phenylmagnesium bromide-d5 (84783-81-3)

Guidance literature:

In diethyl ether;

Reference yield: 91.0%

C5(CH3)5RhBr2P(C6H4CH3)3 (90624-44-5) + phenylmagnesium bromide-d5 (84783-81-3) → C5(CH3)5RhP(C6H4CH3)3(C6(2)H5)Br (90624-63-8)

Guidance literature:

With NH₄Br; In tetrahydrofuran; To a soln. of complex in THF at -40°C the Grignard reagent was added dropwise with a syringe, the mixt. was stirred for 15 min at this temp., allowed to warm to 25°C over 30 min, stirred for 30 min at 25°C, (N2 atm.);; NH4X was added, solvent was removed, ppt. was extd. with CH2Cl2, filtered, concd., chromd. on SiO2 thick-layer plates with CH2Cl2, recrystd. from hexane (-40°C, 1 h), dried in vac.;;

upstream raw materials:

bromobenzene-d5

Downstream raw materials:

[phenyl-2H₅]phenylethyl alcohol

(<(2)H5>phenyl)diphenylmethanol

1-(m-methoxyphenyl)-1-pentadeuterophenylpropanol

(C₆⁽²⁾H₅)2PC₂H₄P(C₆⁽²⁾H₅)2