Fe(CO)3(C₂H₄)(P(C₆H₅)3)

Base Information

• Chemical Name: Fe(CO)3(C₂H₄)(P(C₆H₅)3)
• CAS No.: 84521-08-4
• Molecular Formula: C₂₃H₁₉FeO₃P
• Molecular Weight: 430.223
• Mol file: 84521-08-4.mol

Synonyms:Fe(CO)3(C₂H₄)(P(C₆H₅)3)

Chemical Property of Fe(CO)3(C₂H₄)(P(C₆H₅)3)

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Fe(CO)3(C₂H₄)(P(C₆H₅)3)

There total 3 articles about Fe(CO)3(C₂H₄)(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

C21H15FeO3P(2-) (91879-24-2) + ethylene 1,2-bistriflate (18928-34-2) → fac-tricarbonyl(η2-ethene)(triphenylphosphine)iron (84521-08-4)

Guidance literature:

In diethyl ether; byproducts: CF3SO3(1-); addn. of triflate soln. to carbonylate suspension at -30°C, react. for 12 h (Ar); evapn. (vac.), treatment with pentane, decantation, concn. of soln., pptn., recrystn. (pentane, -25°C); elem. anal.;

Reference yield:

Fe2(CO)6(C2H4)2 (84520-96-7) → Fe(CO)3(C2H4)(P(C6H5)3) (84521-08-4)

Guidance literature:

With triphenylphosphine; In methyl cyclohexane; addn. of PPh3, warming to 25°C; detected by IR, not isolated;

DOI:10.1021/ja00342a076

Reference yield:

bisethylene iron tricarbonyl (74278-01-6) → tricarbonyl bis(triphenylphosphine) iron (14741-34-5,21255-52-7) + Fe(CO)3(C2H4)(P(C6H5)3) (84521-08-4)

Guidance literature:

With P(C₆H₅)3; In not given; all manipulations under N2 or Ar; reaction in an alkane soln. at room temp.; detd. by IR;

DOI:10.1021/ic00251a010

upstream raw materials:

C₂₁H₁₅FeO₃P^(2-)

ethylene 1,2-bistriflate

bisethylene iron tricarbonyl

Fe₂(CO)6(C₂H₄)2