(9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

Base Information

Chemical Name:(9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one
CAS No.:1037069-29-6
Molecular Formula:C₂₉H₄₉NO₃SSi
Molecular Weight:519.864
Hs Code.:

Synonyms:(9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

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Chemical Property of (9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

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Technology Process of (9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

There total 1 articles about (9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: C₂₉H₅₁NO₃SSi

: 1037069-29-6
(9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique;
DOI:10.1002/ejoc.201301461 DOI:10.1002/ejoc.201301461

Reference yield: 80.0%

: 1037069-29-6
(9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

: 1037069-39-8
(2R,5R,6S)-5,6-diisopropyl-2-(pent-4-enyl)-3-[(R)-N-methyl-S-phenylsulfonimidoyl]-5,6-dihydro-2H-pyran-2-ol

Guidance literature:: With hydrogenchloride; acetic acid; In tetrahydrofuran; water; at 20 ℃; for 3h; Inert atmosphere; Schlenk technique;
DOI:10.1002/ejoc.201301461 DOI:10.1002/ejoc.201301461

Reference yield:

: 1037069-29-6
(9R,10S,E)-9-isopropyl-11-methyl-7-[(R)-N-methyl-S-phenyl-sulfonimidoyl]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one

: 1037069-54-7
(2S,3R,6S,8S)-8-chloro-2,3-diisopropyl-5-[(R)-N-methyl-S-phenylsulfonimidoyl](phenylsulfonyl)-1-oxaspiro[5.5]undec-4-ene

: 1037069-55-8
(2S,3R,6R,9S)-9-chloro-2,3-diisopropyl-5-[(R)-N-methyl-S-phenylsulfonimidoyl]-1-oxaspiro[5.5]undec-4-ene

Guidance literature:: Multi-step reaction with 2 steps

1: acetic acid; hydrogenchloride / tetrahydrofuran; water / 3 h / 20 °C / Inert atmosphere; Schlenk technique

2: titanium tetrachloride / dichloromethane / 2 h / -78 °C / Inert atmosphere; Schlenk technique

With hydrogenchloride; titanium tetrachloride; acetic acid; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.201301461