(2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

Base Information

Chemical Name:(2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane
CAS No.:250229-67-5
Molecular Formula:C₃₁H₄₈O₃Si
Molecular Weight:496.806
Hs Code.:

Synonyms:(2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

Suppliers and Price of (2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

There total 1 articles about (2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 110-87-2
3,4-dihydro-2H-pyran

: 250229-65-3
(2S,3S,7R)-8-tert-butyldiphenylsilyloxy-3,7-dimethyl-2-octanol

: 250229-67-5
(2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

Guidance literature:: With toluene-4-sulfonic acid; In diethyl ether; for 4h;
DOI:10.1002/(sici)1099-0690(199909)1999:9<2175::aid-ejoc2175>3.0.co;2-v

Reference yield:

: 250229-67-5
(2R,6S,7S)-1-tert-butyldiphenylsilyloxy-7-tetrahydropyranyloxy-2,6-dimethyloctane

: 250229-69-7
(2R,6S,7S)-7-tetrahydropyranyloxy-2,6-dimethyloctyl tosylate

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / Bu₄NF / tetrahydrofuran / 12 h / 20 °C

2: pyridine / 15 h / 0 °C

With tetrabutyl ammonium fluoride; In tetrahydrofuran; pyridine; 1: Desilylation / 2: Tosylation;
DOI:10.1002/(sici)1099-0690(199909)1999:9<2175::aid-ejoc2175>3.0.co;2-v