3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Base Information

Chemical Name:3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate
CAS No.:83136-12-3
Molecular Formula:C₂₀H₂₁NO₃S
Molecular Weight:355.458
Hs Code.:

3-phenyl-3-aza-endo-tricyclo<3.2.1.0<sup>2,4</sup>>oct-anti-8-yl p-toluenesulfonate

Synonyms:3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

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Chemical Property of 3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

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Technology Process of 3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

There total 7 articles about 3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 98-59-9
p-toluenesulfonyl chloride

: 83198-45-2
3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>octan-anti-8-ol

: 83136-12-3
3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Guidance literature:: In pyridine; at 25 ℃; for 13h;
DOI:10.1021/ja00387a044

Reference yield:

: 875-04-7
7,7-dimethoxybicyclo<2.2.1>hept-2-ene

: 83136-12-3
3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Guidance literature:: Multi-step reaction with 6 steps

1: 82 percent / p-toluenesulfonic acid / benzene / Heating

2: 64 percent / 15 h / 50 - 60 °C

3: 44 percent / decahydronaphthalene / 1.5 h / 165 - 170 °C

4: n-Bu₄NClO₄ / dimethylformamide / electrochemical reduction

5: 93 percent / NaBH₄ / ethanol / 18 h / 0 - 5 °C

6: 38 percent / pyridine / 13 h / 25 °C

With sodium tetrahydroborate; tetrabutylammonium perchlorate; toluene-4-sulfonic acid; In pyridine; ethanol; N,N-dimethyl-formamide; decalin; benzene;
DOI:10.1021/ja00387a044

Reference yield:

: 83198-44-1
3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>octan-8-one

: 83136-12-3
3-phenyl-3-aza-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / NaBH₄ / ethanol / 18 h / 0 - 5 °C

2: 38 percent / pyridine / 13 h / 25 °C

With sodium tetrahydroborate; In pyridine; ethanol;
DOI:10.1021/ja00387a044