methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside
• CAS No.: 1138457-33-6
• Molecular Formula: C₃₆H₃₉NO₁₆
• Molecular Weight: 741.703
• Mol file: 1138457-33-6.mol

Synonyms:methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside

Chemical Property of methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside

There total 1 articles about methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

C22H21NO7 (1138457-31-4) + dodecyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside (495394-47-3) → methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside (1138457-33-6)

Guidance literature:

With 2,6-di-tert-butyl-4-methylpyridine; 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; In dichloromethane; at -78 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.carres.2008.11.008

Reference yield: 72.0%

methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-glucopyranoside (1138457-33-6) → methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-6-O-benzyl-2-deoxy-2-phthalimido-α-D-glucopyranoside (1138457-34-7)

Guidance literature:

With hydrogenchloride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether;

DOI:10.1016/j.carres.2008.11.008

upstream raw materials:

C₂₂H₂₁NO₇

dodecyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside

Downstream raw materials:

methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->3)-6-O-benzyl-2-deoxy-2-phthalimido-α-D-glucopyranoside