Ethanone, 1-[5-(1,1-dimethylethyl)-2,3-dihydroxyphenyl]- (9CI)

Base Information

• Chemical Name: Ethanone, 1-[5-(1,1-dimethylethyl)-2,3-dihydroxyphenyl]- (9CI)
• CAS No.: 84296-64-0
• Molecular Formula: C12H16 O3
• Molecular Weight: 208.25364
• Mol file: 84296-64-0.mol

Synonyms:Ethanone, 1-[5-(1,1-dimethylethyl)-2,3-dihydroxyphenyl]- (9CI)

Chemical Property of Ethanone, 1-[5-(1,1-dimethylethyl)-2,3-dihydroxyphenyl]- (9CI)

Chemical Property:

• Melting Point: 82–83°C
• PSA: 57.53000
• LogP: 2.59790

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethanone, 1-[5-(1,1-dimethylethyl)-2,3-dihydroxyphenyl]- (9CI)

There total 2 articles about Ethanone, 1-[5-(1,1-dimethylethyl)-2,3-dihydroxyphenyl]- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

4-t-butyl-1,2-benzoquinone (1129-21-1) + acetaldehyde (75-07-0,9002-91-9) → 1-(5-tert-Butyl-2,3-dihydroxy-phenyl)-ethanone (84296-64-0) + Acetic acid 5-tert-butyl-2-hydroxy-phenyl ester + Acetic acid 4-tert-butyl-2-hydroxy-phenyl ester

Guidance literature:

In benzene; Title compound not separated from byproducts; Irradiation;

DOI:10.1246/bcsj.55.3657

Reference yield: 7.0%

4-t-butyl-1,2-benzoquinone (1129-21-1) + acetaldehyde (75-07-0,9002-91-9) → 1-(5-tert-Butyl-2,3-dihydroxy-phenyl)-ethanone (84296-64-0) + Acetic acid 5-tert-butyl-2-hydroxy-phenyl ester + Acetic acid 4-tert-butyl-2-hydroxy-phenyl ester + Acetic acid 3-acetyl-5-tert-butyl-2-hydroxy-phenyl ester

Guidance literature:

With di-tert-butyl peroxide; In benzene; Irradiation;

DOI:10.1246/bcsj.55.3657

Reference yield: 25.0%

acetaldehyde (75-07-0,9002-91-9) + 1-(5-tert-Butyl-2,3-dihydroxy-phenyl)-ethanone (84296-64-0) → Acetic acid 3-acetyl-5-tert-butyl-2-hydroxy-phenyl ester

Guidance literature:

With di-tert-butyl peroxide; In benzene; at 38 ℃; for 1h;

DOI:10.1246/bcsj.55.3657

upstream raw materials:

4-t-butyl-1,2-benzoquinone

acetaldehyde