N1-BENZYLETHANE-1,2-DIAMINE

Base Information

• Chemical Name: N1-BENZYLETHANE-1,2-DIAMINE
• CAS No.: 822-77-5
• Molecular Formula: C₇H₉Cl
• Molecular Weight: 128.601
• Mol file: 822-77-5.mol

Synonyms:Bicyclo[2.1.1]hexane,5-chloro-6-methylene-, exo- (7CI)

Chemical Property of N1-BENZYLETHANE-1,2-DIAMINE

Chemical Property:

• Vapor Pressure: 0.0129mmHg at 25°C
• Boiling Point: 259.5°C at 760 mmHg
• Flash Point: 127.6°C
• PSA: 0.00000
• Density: 1.11±0.1 g/cm3(Predicted)
• LogP: 2.18980
• Water Solubility.: negligible

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): R34:
• Hazard Codes: C:Corrosive
• Statements: R34:
• Safety Statements: S23:; S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N1-BENZYLETHANE-1,2-DIAMINE

There total 6 articles about N1-BENZYLETHANE-1,2-DIAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

syn-7-Chlor-α-diazo-norcampher → exo-5-Chlor-6-methylen-bicyclo<2.1.1>hexan (822-77-5)

Guidance literature:

Multi-step reaction with 5 steps

1: H₂O / dioxane / Irradiation

2: (i) oxalyl chloride, benzene, (ii) /BRN= 605257/, Et₂O

3: LiAlH₄ / diethyl ether

4: H₂O₂ / methanol

5: (pyrolysis)

With lithium aluminium tetrahydride; water; dihydrogen peroxide; In 1,4-dioxane; methanol; diethyl ether;

DOI:10.1021/jo01035a006

Reference yield:

3-Tosylhydrazon des syn-7-Chlor-norcampherchinons → exo-5-Chlor-6-methylen-bicyclo<2.1.1>hexan (822-77-5)

Guidance literature:

Multi-step reaction with 6 steps

1: aq. NaOH

2: H₂O / dioxane / Irradiation

3: (i) oxalyl chloride, benzene, (ii) /BRN= 605257/, Et₂O

4: LiAlH₄ / diethyl ether

5: H₂O₂ / methanol

6: (pyrolysis)

With sodium hydroxide; lithium aluminium tetrahydride; water; dihydrogen peroxide; In 1,4-dioxane; methanol; diethyl ether;

DOI:10.1021/jo01035a006

Reference yield:

exo-5-Chlor-exo-dimethylaminomethyl-bicyclo<2.1.1>hexan → exo-5-Chlor-6-methylen-bicyclo<2.1.1>hexan (822-77-5)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂O₂ / methanol

2: (pyrolysis)

With dihydrogen peroxide; In methanol;

DOI:10.1021/jo01035a006