TiCp[1,2-C₆H₄(NCH₂(t)Bu)2](C₆F₅

Base Information

• Chemical Name: TiCp[1,2-C₆H₄(NCH₂(t)Bu)2](C₆F₅
• CAS No.: 884487-95-0
• Molecular Formula: C₂₇H₃₁F₅N₂Ti
• Molecular Weight: 526.429
• Mol file: 884487-95-0.mol

Synonyms:TiCp[1,2-C₆H₄(NCH₂(t)Bu)2](C₆F₅

Chemical Property of TiCp[1,2-C₆H₄(NCH₂(t)Bu)2](C₆F₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of TiCp[1,2-C₆H₄(NCH₂(t)Bu)2](C₆F₅

There total 1 articles about TiCp[1,2-C₆H₄(NCH₂(t)Bu)2](C₆F₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

(η5-cyclopentadienyl)(N,N'-bis(neopentyl)-1,2-phenylenediamido)chlorotitanium (830323-29-0) + bromopentafluorobenzene (344-04-7) → TiCp[1,2-C6H4(NCH2(t)Bu)2](C6F5 (884487-95-0)

Guidance literature:

With (n)BuLi; In hexane; byproducts: LiCl, Br(n)Bu; under Ar; LiC6F5 prepd. in situ by a react. of Br(C6F5) (0.867 mmol) andLo(n)Bu (0.87 mmol) in hexane at -78°C; then Ti-contg. compd. (0 .87 mmol) was added dropwise to the stirring react. mixt.; warming to room temp. and stirring for 12 h; the white ppt. was filtered and the resulting soln. cooled to -40°C; elem. anal.;

DOI:10.1021/om051088y

upstream raw materials:

(η5-cyclopentadienyl)(N,N'-bis(neopentyl)-1,2-phenylenediamido)chlorotitanium

bromopentafluorobenzene