3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

Base Information

Chemical Name:3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene
CAS No.:1315608-52-6
Molecular Formula:C₃₂H₂₆O₂
Molecular Weight:442.557
Hs Code.:

Synonyms:3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

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Chemical Property of 3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

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Technology Process of 3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

There total 5 articles about 3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 888728-75-4
3,6-dibromo-9,10-bis-methoxyphenanthrene

: 1315608-52-6
3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

Guidance literature:: With palladium diacetate; 1-[phenyl(piperidin-1-yl)methyl]naphthalen-2-ol; In N,N-dimethyl acetamide; at 20 ℃; Inert atmosphere;

styrene; 3,6-dibromo-9,10-bis-methoxyphenanthrene; With tetrabutylammomium bromide; potassium carbonate; In N,N-dimethyl acetamide; at 100 - 140 ℃; Inert atmosphere;
DOI:10.3998/ark.5550190.0012.902

Reference yield:

: 84-11-7
9,10-phenanthrenequinone

: 1315608-52-6
3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

Guidance literature:: Multi-step reaction with 4 steps

1.1: bromine; dibenzoyl peroxide / nitrobenzene / 1 h / 75 °C / Irradiation

2.1: sodium dithionite; tetrabutylammomium bromide / tetrahydrofuran; water / 0.5 h

3.1: sodium hydroxide / tetrahydrofuran; water / 0.3 h

4.1: palladium diacetate; 1-[phenyl(piperidin-1-yl)methyl]naphthalen-2-ol / N,N-dimethyl acetamide / 20 °C / Inert atmosphere

4.2: 100 - 140 °C / Inert atmosphere

With sodium dithionite; tetrabutylammomium bromide; bromine; palladium diacetate; sodium hydroxide; 1-[phenyl(piperidin-1-yl)methyl]naphthalen-2-ol; dibenzoyl peroxide; In tetrahydrofuran; N,N-dimethyl acetamide; water; nitrobenzene; 4.2: Mizoroki-Heck reaction;
DOI:10.3998/ark.5550190.0012.902

Reference yield:

: 53348-05-3
3,6-dibromo-phenanthrene-9,10-dione

: 1315608-52-6
3,6-di((E)-styryl)-9,10-bis-methoxyphenanthrene

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium dithionite; tetrabutylammomium bromide / tetrahydrofuran; water / 0.5 h

2.1: sodium hydroxide / tetrahydrofuran; water / 0.3 h

3.1: palladium diacetate; 1-[phenyl(piperidin-1-yl)methyl]naphthalen-2-ol / N,N-dimethyl acetamide / 20 °C / Inert atmosphere

3.2: 100 - 140 °C / Inert atmosphere

With sodium dithionite; tetrabutylammomium bromide; palladium diacetate; sodium hydroxide; 1-[phenyl(piperidin-1-yl)methyl]naphthalen-2-ol; In tetrahydrofuran; N,N-dimethyl acetamide; water; 3.2: Mizoroki-Heck reaction;
DOI:10.3998/ark.5550190.0012.902