ReCl₂(NO)(P(C₆H₅)3)3

Base Information

• Chemical Name: ReCl₂(NO)(P(C₆H₅)3)3
• CAS No.: 83095-51-6
• Molecular Formula: C₅₄H₄₅Cl₂NOP₃Re
• Molecular Weight: 1073.99
• Mol file: 83095-51-6.mol

Synonyms:ReCl₂(NO)(P(C₆H₅)3)3

Chemical Property of ReCl₂(NO)(P(C₆H₅)3)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of ReCl₂(NO)(P(C₆H₅)3)3

There total 1 articles about ReCl₂(NO)(P(C₆H₅)3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[ReH2(NO)(P(C6H5)3)3] (58694-74-9) → ReCl2(NO)(P(C6H5)3)3 (83095-51-6)

Guidance literature:

With PPh₃; HCl; In ethanol; reagents were heated under reflux in EtOH for 15 min; ppt. was filtered off, washed with EtOH and hexane;elem.anal.;

Reference yield: 97.0%

ReCl2(NO)(P(C6H5)3)3 (83095-51-6) → ReCl2(CO)(nitrosyl)(triphenylphosphine)2 (53495-46-8)

Guidance literature:

With CO; In dichloromethane; CO was bubbled into CH2Cl2 for 10 min, after which time the complex wasadded, CO was bubbled for a further 15 min; EtOH was added, solvent was removed, ppt. was recrystd. from CH2Cl2-EtOH;elem.anal.;

Reference yield: 91.0%

ReCl2(NO)(P(C6H5)3)3 (83095-51-6) + para-methylbenzonitrile (104-85-8) → [ReCl2(CNC7H7)2(NO)(P(C6H5)3)] (83114-89-0)

Guidance literature:

In benzene; mixt. of reagents were heated under reflux for 10 min; EtOH was added, solvent was removed, ppt. was recrystd. from CH2Cl2-EtOH;elem.anal.;

upstream raw materials:

[ReH₂(NO)(P(C₆H₅)3)3]

Downstream raw materials:

ReCl₂(CO)(nitrosyl)(triphenylphosphine)2

[ReCl₂(CNC₇H₇)2(NO)(P(C₆H₅)3)]

Refernces