9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

Base Information

Chemical Name:9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene
CAS No.:494760-38-2
Molecular Formula:C₅₉H₇₆O₁₂
Molecular Weight:977.245
Hs Code.:

9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-<i>b</i>]naphthalene

Synonyms:9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

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Chemical Property of 9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

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Technology Process of 9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

There total 31 articles about 9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 494760-43-9
C₆H₅CH₂O(CH₂)3C₁₁H₁₂O₃(CH₃)2(OCH₂C₆H₅)(OCHCHCH₂Sn(C₄H₉)3)CH₂CH(OCOCH₂Cl)OC₁₄H₁₇O₅(CH₃)2(CHCH₂)C₆H₅

: 494760-38-2
9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

: 494760-44-0
9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

Guidance literature:: With 4 A molecular sieve; boron trifluoride diethyl etherate; In dichloromethane; acetonitrile; at -40 - 20 ℃; for 4h;
DOI:10.1021/ja036984k

Reference yield: 56.0%

: C₇₃H₁₀₅ClO₁₄Sn

: 494760-38-2
9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

: 494760-44-0
9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

Guidance literature:: With boron trifluoride diethyl etherate; In acetonitrile; at -40 - 20 ℃; for 4h;
DOI:10.1021/ja028726d

Reference yield:

: 361534-79-4
((2R,4aR,6R,7S,8aR,9aS,10aS)-6-Hydroxy-6,10a-dimethyl-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid ethyl ester

: 494760-38-2
9-[10-benzyloxy-8-(3-benzyloxy-propyl)-10a,11a-dimethyl-2-vinyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-yloxy]-9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene

Guidance literature:: Multi-step reaction with 16 steps

1.1: LiAlH₄ / diethyl ether / 1 h / 0 °C

2.1: 1.56 g / 2,6-lutidine / CH₂Cl₂ / 2 h / Heating

3.1: 100 percent / H₂ / Pd(OH)2-C / ethyl acetate / 49 h

4.1: 599 mg / Et₃N / CH₂Cl₂ / 3 h / Heating

5.1: 95 percent / CuBr / tetrahydrofuran; diethyl ether / 1 h / -20 - 20 °C

6.1: O₃(g) / methanol; CH₂Cl₂ / -78 °C

6.2: Me₂S; NaBH₄ / methanol; CH₂Cl₂ / 1 h / 0 °C

7.1: 2.13 g / pyridine / CH₂Cl₂ / 20 °C

8.1: O₃(g) / methanol; CH₂Cl₂ / -78 °C

8.2: NaBH₄ / methanol; CH₂Cl₂ / 1 h / 20 °C

9.1: CSA / CH₂Cl₂ / 1 h / 0 °C

10.1: 2.03 g / aq. AcOH / tetrahydrofuran / 3 h / 30 °C

11.1: 2-nitrophenyl selenocyanate; Bu₃P / tetrahydrofuran / 0.5 h / 20 °C

11.2: 97 percent / NaHCO₃; aq. H₂O₂ / tetrahydrofuran / 1 h / 40 °C

12.1: 100 percent / TBAF / tetrahydrofuran / 14 h / Heating

13.1: Et₃N; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 2 h / 40 °C

13.2: 90 percent / DMAP / toluene / 0.5 h / 40 °C

14.1: 99 percent / TBAF / tetrahydrofuran / 3 h / 20 °C

With pyridine; 2,6-dimethylpyridine; lithium aluminium tetrahydride; ortho-nitrophenyl selenocyanate; tributylphosphine; 2,4,6-trichlorobenzoyl chloride; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; hydrogen; ozone; acetic acid; triethylamine; copper(I) bromide; palladium hydroxide - carbon; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1021/ja036984k