4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

Base Information

Chemical Name:4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine
CAS No.:1373128-05-2
Molecular Formula:C₁₈H₁₄F₃NS
Molecular Weight:333.377
Hs Code.:

Synonyms:4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

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Chemical Property of 4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

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Technology Process of 4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

There total 1 articles about 4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 78905-08-5
<(o-methylthio)phenyl>acetylene

: 134481-25-7
2,2,2-Trifluoro-N-p-tolyl-acetimidoyl iodide

: 1373128-05-2
4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 20 ℃; Inert atmosphere;
DOI:10.1016/j.jorganchem.2012.02.009

Reference yield:

: 1373128-05-2
4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: C₂₁H₁₆F₃NO₂S

Guidance literature:: With bis(benzonitrile)palladium(II) dichloride; p-benzoquinone; lithium chloride; In tetrahydrofuran; at 70 ℃; for 5h; stereoselective reaction; Inert atmosphere;
DOI:10.1016/j.jorganchem.2012.02.009

Reference yield:

: 1373128-05-2
4-methylphenyl-[3-(2-methylthiophenyl)-1-trifluoromethylprop-2-ynylidene]amine

: 1373127-99-1
(E)-methyl 3-(2-(2,2,2-trifluoro-1-p-tolylethylamino)benzo[b]thiophen-3-yl)acrylate

Guidance literature:: Multi-step reaction with 2 steps

1: bis(benzonitrile)palladium(II) dichloride; p-benzoquinone; lithium chloride / tetrahydrofuran / 5 h / 70 °C / Inert atmosphere

2: sodium cyanoborohydride / methanol; acetic acid / 1.25 h / 0 °C / Inert atmosphere

With bis(benzonitrile)palladium(II) dichloride; sodium cyanoborohydride; p-benzoquinone; lithium chloride; In tetrahydrofuran; methanol; acetic acid;
DOI:10.1016/j.jorganchem.2012.02.009