methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Base Information

Chemical Name:methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside
CAS No.:130144-24-0
Molecular Formula:C₃₅H₄₀O₁₆
Molecular Weight:716.693
Hs Code.:

Synonyms:methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Suppliers and Price of methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

There total 3 articles about methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: Benzoic acid (2R,4aR,6S,7R,8S,8aR)-8-((2S,3aR,5R,6R,7S,7aR)-6,7-diacetoxy-5-acetoxymethyl-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran-2-yloxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

: 130144-24-0
methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃;
DOI:10.1021/jo981135e

Reference yield: 59.0%

: 28642-64-0,35823-97-3,38992-99-3,51591-23-2,55169-75-0,56253-26-0,72659-78-0,80041-30-1,80299-59-8,86420-70-4,86420-72-6,91685-06-2,99265-94-8,109010-33-5,118246-05-2,126255-07-0
methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 130144-24-0
methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Guidance literature:: With 4 A molecular sieve; mercury(II) cyanide; mercury dibromide; In acetonitrile; for 2h; Ambient temperature;
DOI:10.1071/CH9900665

Reference yield:

: 28642-64-0,35823-97-3,38992-99-3,51591-23-2,55169-75-0,56253-26-0,72659-78-0,80041-30-1,80299-59-8,86420-70-4,86420-72-6,91685-06-2,99265-94-8,109010-33-5,118246-05-2,126255-07-0
methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside

: 604-69-3
β-D-glucose pentaacetate

: 130144-24-0
methyl 2-O-benzoyl-4,6-benzylidene-3-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-D-glucoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; Yield given. Multistep reaction; 1.) dichloromethane, RT, 1 h, 2.) 6 h;
DOI:10.1071/CH9900665