RhCl(CO){P(o-ClC₆H₄)Ph₂}2

Base Information

Chemical Name:RhCl(CO){P(o-ClC₆H₄)Ph₂}2
CAS No.:124020-53-7
Molecular Formula:C₃₇H₂₈Cl₃OP₂Rh
Molecular Weight:759.841
Hs Code.:

RhCl(CO){P(o-ClC<sub>6</sub>H<sub>4</sub>)Ph<sub>2</sub>}2

Synonyms:RhCl(CO){P(o-ClC₆H₄)Ph₂}2

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Chemical Property of RhCl(CO){P(o-ClC₆H₄)Ph₂}2

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Technology Process of RhCl(CO){P(o-ClC₆H₄)Ph₂}2

There total 4 articles about RhCl(CO){P(o-ClC₆H₄)Ph₂}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 124003-65-2
RhCl(η2-PCCl)(η1-PCCl)

: 124020-53-7
RhCl(CO){P(o-ClC₆H₄)Ph₂}2

Guidance literature:: With carbon monoxide; In ethanol; under argon, CO slowly bubbled through the solution for 40 min, filtered, washed (hexane), dissolved in chloroform; chromatographed (silica gel in hexane), eluted with CHCl3/hexane (2/1), evaporated the pale yellow band, recrystd. from CH2Cl2/n-hexane;;
DOI:10.1016/0022-328X(88)83152-8

Reference yield: 77.0%

: rhodium(III) chloride trihydrate

: 35035-62-2
diphenyl (2‐chlorophenyl) phosphine

: 124020-53-7
RhCl(CO){P(o-ClC₆H₄)Ph₂}2

Guidance literature:: With carbon monoxide; In ethanol; under argon, at 25°C, CO bubbled slowly through the solution for 4 h, CO athmosphere maintained for 12 h, filtered, washed (hexane), dissolved in chloroform; chromatographed (silica gel in hexane), eluted with CHCl3/hexane (2/1), evaporated the pale yellow band, recrystd. from CH2Cl2/n-hexane; elem. anal., NMR;
DOI:10.1016/0022-328X(88)83152-8

Reference yield: 40.0%

: RhCl2(PC)(η2-PCCl)

: 124020-53-7
RhCl(CO){P(o-ClC₆H₄)Ph₂}2

Guidance literature:: With carbon monoxide; sodium naphthalenide; In tetrahydrofuran; under argon, at 0°C, sodium naphthalenide solution added dropwise, stirred for 10 min, CO bubbled through for 30 min, evaporated to dryness, dissolved in chloroform; chromatographed on silica gel in hexane, eluted with chloroform/hexane (1/1), the pale yellow band evaporated to dryness, recrystd. from chloroform/n-hexane;
DOI:10.1016/0022-328X(88)83152-8