(+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

Base Information

Chemical Name:(+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane
CAS No.:125372-54-5
Molecular Formula:C₂₆H₃₆O₆S₄
Molecular Weight:572.832
Hs Code.:

Synonyms:(+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

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Chemical Property of (+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

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Technology Process of (+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

There total 1 articles about (+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 626-04-0
3-mercaptothiophenol

: 73893-12-6
(1S,2S)-1,2-Bis-tosyloxymethyl-18-krone-6

: 125372-54-5
(+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

Guidance literature:: With potassium hydroxide; In tetrahydrofuran; ethanol; at 50 ℃; for 2h;
DOI:10.1248/cpb.37.912

Reference yield:

: 125372-54-5
(+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

: (S)-2-Benzoylamino-thiopropionic acid S-(3-{(2R,3R)-3-[2-(2-benzyloxycarbonylamino-acetylsulfanyl)-phenylsulfanylmethyl]-1,4,7,10,13,16-hexaoxa-cyclooctadec-2-ylmethylsulfanyl}-phenyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Et₃N, 2.) pyridine / 1.) EtOH, room t., 30 min, 2.) acetone, room t., 15 min

2: Et₃N / CHCl₃

With pyridine; triethylamine; In chloroform;
DOI:10.1248/cpb.37.912

Reference yield:

: 1738-86-9
Z-Gly-ONp

: 5673-65-4
L-alanine p-nitrophenyl ester hydrobromide

: 125372-54-5
(+)-(2S,3S)-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

: 125372-65-8
Benzyloxycarbonylamino-thioacetic acid S-(3-{(2R,3R)-3-[3-(2-benzyloxycarbonylamino-acetylsulfanyl)-phenylsulfanylmethyl]-1,4,7,10,13,16-hexaoxa-cyclooctadec-2-ylmethylsulfanyl}-phenyl) ester

: (2S,3S)-S-(N-carbobenzyloxyglycyl)-S'-L-alanyl-2,3-bis(3-mercaptophenylthiomethyl)-1,4,7,10,13,16-hexaoxacyclooctadecane

Guidance literature:: With pyridine; triethylamine; Yield given. Multistep reaction. Yields of byproduct given; 1.) EtOH, room t., 30 min, 2.) acetone, room t., 15 min;
DOI:10.1248/cpb.37.912