Technology Process of C15H20O2
There total 3 articles about C15H20O2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride;
In
dichloromethane;
at 40 ℃;
for 2h;
Inert atmosphere;
DOI:10.1021/ol3007259
- Guidance literature:
-
Multi-step reaction with 2 steps
1: methanol; lithium borohydride / diethyl ether / 0 - 20 °C
2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2 h / 40 °C / Inert atmosphere
With
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; methanol; lithium borohydride;
In
diethyl ether; dichloromethane;
DOI:10.1021/ol3007259
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: titanium tetrachloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 2 h / -40 °C / Inert atmosphere
1.2: 2.25 h / -78 - -20 °C / Inert atmosphere
2.1: methanol; lithium borohydride / diethyl ether / 0 - 20 °C
3.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2 h / 40 °C / Inert atmosphere
With
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; methanol; lithium borohydride; titanium tetrachloride; N-ethyl-N,N-diisopropylamine;
In
diethyl ether; dichloromethane;
DOI:10.1021/ol3007259
