1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

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Chemical Name:1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane
CAS No.:200863-92-9
Molecular Formula:C₇₁H₇₄N₂O₁₈
Molecular Weight:1243.37
Hs Code.:

Synonyms:1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

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Chemical Property of 1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

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Technology Process of 1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

There total 8 articles about 1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 4-(4-Methoxy-benzyloxycarbonylamino)-cyclohexanecarboxylic acid

: 1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-undecanediol

: 200863-92-9
1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 96h; Ambient temperature;
DOI:10.1016/S0040-4020(97)10196-X

Reference yield:

: 672-13-9
2-hydroxy-5-methoxybenzaldehyde

: 200863-92-9
1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

Guidance literature:: Multi-step reaction with 7 steps

1: 85 percent / diisopropyl ethylamine / CH₂Cl₂ / 4 h / Ambient temperature

2: 1.) Mg, I₂ / 1.) THF, reflux, 1.5 h, 2.) THF, room temperature, 3 h

3: diisopropyl ethylamine / CH₂Cl₂ / 5 h / Ambient temperature

4: LiClO₄, NaOAc / anodic oxidation at 1.3 V

5: LDA / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) room temperature, 6 h

6: 90 percent / BCl₃ / CH₂Cl₂ / 1.) -78 deg C, 1 h, 2.) room temperature, 2 h

7: 91 percent / DCC, DMAP / CH₂Cl₂ / 96 h / Ambient temperature

With dmap; iodine; sodium acetate; lithium perchlorate; boron trichloride; magnesium; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(97)10196-X

Reference yield:

: 4549-33-1
1,9-Dibromononane

: 200863-92-9
1,11-bis(1,4-dihydroxyanthracene-9,10-dion-2-yl)-1,11-bis[(trans-4-{N-[(4-methoxybenzyl)oxy]carbonyl}amino)cyclohexylcarbonyloxy]-undecane

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) Mg, I₂ / 1.) THF, reflux, 1.5 h, 2.) THF, room temperature, 3 h

2: diisopropyl ethylamine / CH₂Cl₂ / 5 h / Ambient temperature

3: LiClO₄, NaOAc / anodic oxidation at 1.3 V

4: LDA / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) room temperature, 6 h

5: 90 percent / BCl₃ / CH₂Cl₂ / 1.) -78 deg C, 1 h, 2.) room temperature, 2 h

6: 91 percent / DCC, DMAP / CH₂Cl₂ / 96 h / Ambient temperature

With dmap; iodine; sodium acetate; lithium perchlorate; boron trichloride; magnesium; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(97)10196-X